ThePlanck relation[1][2][3](referred to asPlanck's energy–frequency relation,[4]thePlanck–Einstein relation,[5]Planck equation,[6]andPlanck formula,[7]though the latter might also refer toPlanck's law[8][9]) is a fundamental equation inquantum mechanicswhich states that theenergyEof aphoton,known asphoton energy,is proportional to itsfrequencyν: Theconstant of proportionality,h,is known as thePlanck constant.Several equivalent forms of the relation exist, including in terms ofangular frequencyω: where.Written using the symbolffor frequency, the relation is

The relation accounts for thequantized nature of lightand plays a key role in understanding phenomena such as thephotoelectric effectandblack-body radiation(where the relatedPlanck postulatecan be used to derivePlanck's law).

Spectral forms

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Light can be characterized using severalspectralquantities, such asfrequencyν,wavelengthλ,wavenumber,and their angular equivalents (angular frequencyω,angular wavelengthy,andangular wavenumberk). These quantities are related through so the Planck relation can take the following "standard" forms: as well as the following "angular" forms:

The standard forms make use of thePlanck constanth.The angular forms make use of thereduced Planck constantħ=h/.Herecis thespeed of light.

de Broglie relation

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The de Broglie relation,[10][11][12]also known as de Broglie's momentum–wavelength relation,[4]generalizes the Planck relation tomatter waves.Louis de Broglieargued that ifparticles had a wave nature,the relationE=would also apply to them, and postulated that particles would have a wavelength equal toλ=h/p.Combining de Broglie's postulate with the Planck–Einstein relation leads to or

The de Broglie relation is also often encountered invectorform wherepis the momentum vector, andkis theangular wave vector.

Bohr's frequency condition

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Bohr's frequency condition[13]states that the frequency of a photon absorbed or emitted during anelectronic transitionis related to the energy difference (ΔE) between the twoenergy levelsinvolved in the transition:[14]

This is a direct consequence of the Planck–Einstein relation.

See also

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References

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  1. ^French & Taylor (1978), pp. 24, 55.
  2. ^Cohen-Tannoudji, Diu & Laloë (1973/1977), pp. 10–11.
  3. ^Kalckar, J., ed. (1985), "Introduction",N. Bohr:Collected Works. Volume 6: Foundations of Quantum PhysicsI,(1926–1932),vol. 6, Amsterdam: North-Holland Publ., pp. 7–51,ISBN0 444 86712 0: 39 
  4. ^abSchwinger (2001), p. 203.
  5. ^Landsberg (1978), p. 199.
  6. ^Landé (1951), p. 12.
  7. ^Griffiths, D. J. (1995), pp. 143, 216.
  8. ^Griffiths, D. J. (1995), pp. 217, 312.
  9. ^Weinberg (2013), pp. 24, 28, 31.
  10. ^Weinberg (1995), p. 3.
  11. ^Messiah (1958/1961), p. 14.
  12. ^Cohen-Tannoudji, Diu & Laloë (1973/1977), p. 27.
  13. ^Flowers et al. (n.d), 6.2 The Bohr Model
  14. ^van der Waerden (1967), p. 5.

Cited bibliography

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