Apreservativeis a substance or a chemical that is added to products such as food products, beverages,pharmaceutical drugs,paints, biological samples, cosmetics, wood, and many other products to preventdecompositionbymicrobialgrowth or by undesirablechemical changes.In general, preservation is implemented in two modes, chemical and physical. Chemical preservation entails addingchemical compoundsto the product. Physical preservation entails processes such as refrigeration or drying.[1]Preservativefood additivesreduce the risk offoodborne infections,decrease microbial spoilage, and preserve fresh attributes and nutritional quality. Some physical techniques forfood preservationinclude dehydration, UV-C radiation, freeze-drying, and refrigeration. Chemical preservation and physical preservation techniques are sometimes combined.

Food preservation

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Preservatives have been used since prehistoric times.Smoked meatfor example hasphenolsand other chemicals that delay spoilage. The preservation of foods has evolved greatly over the centuries and has been instrumental in increasing food security. The use of preservatives other than traditional oils, salts, paints,[clarification needed]etc. in food began in the late 19th century, but was not widespread until the 20th century.[2]

The use of food preservatives varies greatly depending on the country. Many developing countries that do not have strong governments to regulate food additives face either harmful levels of preservatives in foods or a complete avoidance of foods that are considered unnatural or foreign. These countries have also proven useful in case studies surrounding chemical preservatives, as they have been only recently introduced.[3]In urban slums of highly populated countries, the knowledge about contents of food tends to be extremely low, despite consumption of these imported foods.[4]

Antimicrobial preservatives

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Antimicrobial preservatives prevent degradation by bacteria. This method is the most traditional and ancient type of preserving—ancient methods such as pickling and adding honey prevent microorganism growth by modifying the pH level. The most commonly used antimicrobial preservative islactic acid.Common antimicrobial preservatives are presented in the table.[5][6][7]Nitratesandnitritesare also antimicrobial.[8]The detailed mechanism of these chemical compounds range from inhibiting growth of the bacteria to the inhibition of specific enzymes.

E number chemical compound comment
E200 – E203 sorbic acid,sodium sorbateand sorbates common forcheese,wine,baked goods, personal care products
E210 – E213 benzoic acidandbenzoates used in acidic foods such asjams,salad dressing,juices,pickles,carbonated drinks,soy sauce
E214 – E219 parabens stable at a broadpHrange
E220 – E228 sulfur dioxideandsulfites common for fruits, wine
E249 – E250 nitrites speed up thecuringof meat and also impart an attractive colour, no effect on botulism bacteria[9][10]
E251 – E252 nitrates used in meats
E270 lactic acid -
E280 – E283 propionic acidandpropionates baked goods
E338 phosphoric acid used in some jams, preserves and carbonated drinks; also used for acidification and for flavouring.

Antioxidants

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Thefree radicalpathway for the first phase of the oxidative rancidification of fats. This process is slowed by antioxidants.

The oxidation process spoils most food, especially those with a high fat content. Fats quicklyturn rancidwhen exposed to oxygen. Antioxidants prevent or inhibit the oxidation process. The most common antioxidant additives areascorbic acid(vitamin C) and ascorbates.[11]Thus, antioxidants are commonly added to oils, cheese, and chips.[5]Other antioxidants include thephenolderivativesBHA,BHT,TBHQandpropyl gallate.These agents suppress the formation of hydroperoxides.[6]

E number chemical compound comment
E300-304 ascorbic acid,sodium ascorbate cheese, chips
E321 butylated hydroxytoluene,butylated hydroxyanisole also used in food packaging
E310-312 gallic acidand sodium gallate oxygen scavenger
E220 – E227 sulfur dioxide and sulfites beverages, wine
E306 – E309 tocopherols vitamin E activity

A variety of agents are added to sequester (deactivate) metal ions that otherwise catalyze the oxidation of fats. Common sequestering agents aredisodium EDTA,citric acid(and citrates),tartaric acid,andlecithin.[1]

Nonsynthetic compounds for food preservation

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Citricandascorbic acidstargetenzymesthat degrade fruits and vegetables, e.g.,mono/polyphenol oxidasewhich turns surfaces of cut apples and potatoes brown.Ascorbic acidandtocopherol,which are vitamins, are common preservatives.Smokingentails exposing food to a variety of phenols, which are antioxidants. Natural preservatives includerosemaryandoreganoextract,[12]hops,salt,sugar,vinegar,alcohol,diatomaceous earthandcastor oil.

Traditional preservatives, such as sodium benzoate have raised health concerns in the past. Benzoate was shown in a study to cause hypersensitivity in some asthma sufferers. This has caused reexamination of natural preservatives which occur in vegetables.[13]

Public awareness of food preservation

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Public awareness of food preservatives is uneven.[14]Americans have a perception that food-borne illnesses happen more often in other countries. This may be true, but the occurrence of illnesses, hospitalizations, and deaths are still high. It is estimated by theCenters for Disease Control(CDC) that each year there are 76 million illnesses, 325,000 hospitalizations, and 5,000 deaths linked to food-borne illness.[15]

Food suppliers are facing difficulties with regards to the safety and quality of their products as a result of the rising demand for ready-to-eat fresh food products. Artificial preservatives meet some of these challenges by preserving freshness for longer periods of time, but these preservatives can cause negative side-effects as well.

Preservation of other products

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Water-based home and personal care products usebroad-spectrumpreservatives, such asisothiazolinonesandformaldehyde releasers,which may cause sensitization, leading toallergicskin.[19]

Substance Use
parabens personal care products
isothiazolinones (MIT,CMIT,BIT) not for food:home and personal care products, paints/coatings
formaldehyde releasers (DMDM hydantoin) not for food:home and personal care products

See also

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References

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  1. ^abErich Lück and Gert-Wolfhard von Rymon Lipinski "Foods, 3. Food Additives" inUllmann's Encyclopedia of Industrial Chemistry,2002, Wiley-VCH, Weinheim.doi:10.1002/14356007.a11_561
  2. ^Evans, G., de Challemaison, B., & Cox, D. N. (2010). "Consumers' ratings of the natural and unnatural qualities of foods".Appetite.54(3): 557–563.doi:10.1016/j.appet.2010.02.014.PMID20197074.S2CID41078790.{{cite journal}}:CS1 maint: multiple names: authors list (link)
  3. ^Ashagrie, Z. Z., & Abate, D. D. (2012). IMPROVEMENT OF INJERA SHELF LIFE THROUGH THE USE OF CHEMICAL PRESERVATIVES. African Journal of Food, Agriculture, Nutrition & Development, 12(5), 6409-6423.
  4. ^Kumar, H., Jha, A., Taneja, K. K., Kabra, K., & Sadiq, H. M. (2013). A STUDY ON CONSUMER AWARENESS, SAFETY PERCEPTIONS & PRACTICES ABOUT FOOD PRESERVATIVES AND FLAVOURING AGENTS USED IN PACKED /CANNED FOODS FROM SOUTH INDIA. National Journal of Community Medicine, 4(3), 402-406.
  5. ^abMsagati, Titus A. M. (2012). The Chemistry of Food Additives and Preservatives. Retrieved fromhttp://www.eblib.comArchived2016-02-07 at theWayback Machine
  6. ^abDalton, Louisa (November 2002)."Food Preservatives".Chemical and Engineering News.80(45): 40.doi:10.1021/cen-v080n045.p040.Archivedfrom the original on 5 April 2019.Retrieved9 February2012.
  7. ^"Using Preservatives".Archivedfrom the original on 28 March 2019.Retrieved9 February2012.
  8. ^Shaw, Ian C. (2012). Food Safety: The Science of Keeping Food Safe. Retrieved fromhttp://www.eblib.comArchived2016-02-07 at theWayback Machine(306- 334)
  9. ^Wilson, Bee (2018-03-01)."Yes, bacon really is killing us".The Guardian.London.ISSN0261-3077.Archivedfrom the original on 2021-02-10.Retrieved2021-02-14.In trade journals of the 1960s, the firms who sold nitrite powders to ham-makers spoke quite openly about how the main advantage was to increase profit margins by speeding up production.
  10. ^Doward, Jamie (2019-03-23)."Revealed: no need to add cancer-risk nitrites to ham".The Observer.London.Archivedfrom the original on 2021-01-26.Retrieved2021-02-14.The results show that there is no change in levels of inoculatedC. botulinumover the curing process, which implies that the action of nitrite during curing is not toxic toC. botulinumspores at levels of 150ppm [parts per million] ingoing nitrite and below.
  11. ^ab(Bhat, Rajeev; Alias, Abd Karim; Paliyath, Gopinadham (2011). Progress in Food Preservation. Retrieved fromhttp://www.eblib.comArchived2016-02-07 at theWayback Machine
  12. ^Riva Pomerantz (Nov 15, 2017). "KOSHER IN THE LAB".Ami.No. 342. p. 88.
  13. ^P'EREZ-D'IAZ, I.M; MCFEETERS, R.F (May 2010)."Preservation of Acidified Cucumbers with a Natural Preservative Combination of Fumaric Acid and Allyl Isothiocyanate that Target Lactic Acid Bacteria and Yeasts".Journal of Food Science.75(4): M204–M208.doi:10.1111/j.1750-3841.2010.01587.x.PMID20546411.Archivedfrom the original on 2021-02-19.Retrieved2018-12-29.
  14. ^Kumar, H. N. Harsha; Jha, Anshu Kumar; Taneja, Khushboo K.; Kabra, Krishan; Sadiq, Hafeez M. (2013). A Study On Consumer Awareness, Safety Perceptions & Practices about Food Preservatives and Flavouring Agents used in Packed/Canned Foods from South India. National Journal of Community Medicine, 4(3), 402.
  15. ^Theron, M. M. & Lues, J. F. (2007). Organic acids and meat preservation: A review. Food Reviews International, 23, 141-158.
  16. ^Field, Simon Quellen (2008).Why There's Antifreeze in Your Toothpaste: The Chemistry of Household Ingredients.Chicago: Chicago Review Press.
  17. ^abAntinoro, L. (2008). EN Rates 12 Common Food Additives As Safe Or Sorry Ingredients. (Cover story). Environmental Nutrition, 31(5), 1-4.
  18. ^Barrett, J. R. (2007)."Hyperactive Ingredients?".Environmental Health Perspectives.115(12): A578.doi:10.1289/ehp.115-a578.PMC2137120.PMID18087571.
  19. ^"The search is on for new cosmetic preservatives".Chemical & Engineering News.Archivedfrom the original on 2021-10-25.Retrieved2021-10-25.
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