Tufais a variety oflimestoneformed whencarbonate mineralsprecipitateout of water inunheatedrivers or lakes.Geothermally heated hot springssometimes produce similar (but less porous) carbonate deposits, which are known astravertineorthermogene travertine.Tufa is sometimes referred to asmeteogene travertine.[1]
Classification and features
editModern and fossil tufa deposits abound with wetland plants;[2]as such, many tufa deposits are characterised by their largemacrobiologicalcomponent, and are highly porous. Tufa forms either in fluvial channels or in lacustrine environments. Ford and Pedley (1996)[3]provide a review of tufa systems worldwide.
Fluvial deposits
editDeposits can be classified by their depositional environment (or otherwise by vegetation orpetrographically). Pedley (1990)[4]provides an extensive classification system, which includes the following classes of fluvial tufa:
- Spring – Deposits form on emergence from aspring/seep.Morphology can vary frommineratrophicwetlands to spring aprons (seecalcareous sinter)
- Braided channel – Deposits form within a fluvial channel, dominated by oncoids (seeoncolite)
- Cascade – Deposits form at waterfalls, deposition is focused here due to accelerated flow (seeGeochemistry)
- Barrage – Deposits form as a series ofphytohermbarrages across a channel, which may grow up to several metres in height. Barrages often contain a significant detrital component, composed of organic material (leaf litter,branches etc.).
Lacustrine deposits
editLacustrine tufas are generally formed at the periphery of lakes and built-up phytoherms (freshwater reefs), and onstromatolites.Oncoidsare also common in these environments.
Calcareous sinter
editAlthough sometimes regarded as a distinct carbonate deposit, calcareous sinter formed from ambient temperature water can be considered a sub-type of tufa.
Speleothems
editCalcareousspeleothemsmay be regarded as a form of calcareous sinter. They lack any significantmacrophytecomponent due to the absence of light, and for this reason they are often morphologically closer to travertine or calcareous sinter.
Columns
editTufa columns are an unusual form of tufa typically associated withsaline lakes.They are distinct from most tufa deposits in that they lack any significantmacrophytecomponent, due to the salinity excludingmesophilic organisms.[3]Some tufa columns may actually form from hot-springs, and may therefore constitute a form oftravertine.It is generally thought that such features form from CaCO3precipitated when carbonate rich source waters emerge into alkaline soda lakes. They have also been found in marine settings in the Ikkafjordof Greenland where theIkaitecolumns can reach up to 18 m (59 ft) in height.[5]
Biology
editTufa deposits form an important habitat for a diverse flora.Bryophytes(mosses, liverworts etc.) anddiatomsare well represented. The porosity of the deposits creates a wet habitat ideal for these plants.
Geochemistry
editModern tufa is formed from alkaline waters, supersaturated with calcite. On emergence, waters degas CO2due to the loweratmosphericpCO2(seepartial pressure), resulting in an increase in pH. Since carbonate solubility decreases with increased pH,[6]precipitation is induced. Supersaturation may be enhanced by factors leading to a reduction inpCO2,for example increased air-water interactions at waterfalls may be important,[7]as may photosynthesis.[8]
Recently it has been demonstrated that microbially induced precipitation may be more important than physico-chemical precipitation. Pedley et al. (2009)[9]showed with flume experiments that precipitation does not occur unless abiofilmis present, despite supersaturation.
Calciteis the dominant mineral precipitate, followed by the polymorpharagonite.[citation needed]
Occurrence
editTufa is common in many parts of the world including:
- Pyramid Lake,Nevada, US – tufa formations
- Big Soda Lake,Nevada, US – tufa formations only a century old
- Mono Lake,California, US – tufa columns
- Trona Pinnacles,California, US – tufa columns
- Sitting Bull Falls,New Mexico, US - tufa waterfall
- Matlock Bath,Derbyshire, United Kingdom
- North Dock Tufa,United Kingdom
- Basturs Lakes,Pallars Jussà,Catalonia– tufa mounds
- Various parts of Armenia, such asArtik
- The southwestern coastline ofWestern Australia
- TheMadikwe Game Reservein theNorth West Province,South Africa
- TheKadishi tufa fall,Blyde River Canyon Nature Reserve,Mpumalanga Province,South Africa
- Various parts of southern Italy.[10]
Some sources suggest that "tufa" was used as the primary building material for most of the châteaux of theLoire Valley,France. This results from a mis-translation of the terms "tuffeaujaune "and" tuffeau blanc ", which are porous varieties of theLate Cretaceousmarine limestone known aschalk.[11][need quotation to verify][12][failed verification]
Dinaric karst watercourses
editUses
editTufa is occasionally shaped into a planter. Its porous consistency makes it ideal foralpine gardens.A concrete mixture calledhypertufais used for similar purposes.
In the 4th century BC, tufa was used to build Roman walls up to 10m high and 3.5m thick.[13]The soft stone allows for easy sculpting. Tufa masonry was used in cemeteries, such as the one inCerveteri.[14]
See also
edit- List of types of limestone– Limestone deposits listed by location
References
edit- ^Pentecost, A. (2005).Travertine.Dordrecht, Netherlands: Kluwer Academic Publishers Group.ISBN1-4020-3523-3.
- ^Koban, C.G.; Schweigert, G. (1993). "Microbial origin of travertine fabrics - two examples from Southern Germany (Pleistocene Stuttgart travertines and Miocene riedöschingen Travertine)".Facies.29:251–263.doi:10.1007/BF02536931.S2CID129353316.
- ^abFord, T.D.; Pedley, H.M. (1996). "A review of tufa and travertine deposits of the world".Earth-Science Reviews.41(3–4): 117–175.Bibcode:1996ESRv...41..117F.doi:10.1016/S0012-8252(96)00030-X.
- ^Pedley, H.M. (1990). "Classification and environmental models of cool freshwater tufas".Sedimentary Geology.68(1–2): 143–154.Bibcode:1990SedG...68..143P.doi:10.1016/0037-0738(90)90124-C.
- ^Buchardt, B.; Israelson, C.; Seaman, P.; Stockmann, G. (2001). "Ikaite tufa towers in ikka fjord, southwest Greenland: their formation by mixing of seawater and alkaline spring water".Journal of Sedimentary Research.71(1): 176–189.Bibcode:2001JSedR..71..176B.doi:10.1306/042800710176.
- ^Bialkowski, S.E. 2004."Use of Acid Distributions in Solubility Problems".Archived fromthe originalon 2009-02-28.
{{cite web}}
:CS1 maint: numeric names: authors list (link) - ^Zhang, D.; Zhang, Y; Zhu, A.; Cheng, X (2001). "Physical mechanisms of river waterfall tufa (travertine) formation".Journal of Sedimentary Research.71(1): 205–216.Bibcode:2001JSedR..71..205Z.doi:10.1306/061600710205.
- ^Riding, R. (2000). "Microbial carbonates: the geological record of calcified bacterial-algal mats and biofilms".Sedimentology.47:179–214.doi:10.1046/j.1365-3091.2000.00003.x.S2CID130272076.
- ^Pedley, M.; Rogerson, M.; Middleton, R. (2009). "Freshwater calcite precipitates from in vitro mesocosm flume experiments: a case for biomediation of tufas".Sedimentology.56(2): 511–527.Bibcode:2009Sedim..56..511P.doi:10.1111/j.1365-3091.2008.00983.x.S2CID129855485.
- ^Ascione, Alessandra; Iannace, Alessandro; Imbriale, Pamela; Santangelo, Nicoletta; Santo, Antonio (February 2014)."Tufa and travertines of southern Italy: deep-seated, fault-related CO 2 as the key control in precipitation".Terra Nova.26(1): 1–13.doi:10.1111/ter.12059.
- ^Forster, A.; Forster, S.C. (1996). "Troglodyte dwellings of the Loire Valley, France".Quarterly Journal of Engineering Geology and Hydrogeology.29(3): 193–197.doi:10.1144/GSL.QJEGH.1996.029.P3.01.S2CID128896993.
- ^"Au Turonien".Une histoire de la Touraine à travers ses roches(in French).Retrieved2010-10-01.
- ^Devereaux, Bret (2021-11-12)."Collections: Fortification, Part II: Romans Playing Cards".A Collection of Unmitigated Pedantry.Retrieved2023-09-15.
- ^Marini, Elena (January 2010)."A Study of the Architectonic Development of the Great Funerary Tumuli in the Etruscan Necropolises of Cerveteri".Etruscan Studies.13(1).doi:10.1515/etst.2010.13.1.3.ISSN2163-8217.