Aprimary batteryorprimary cellis abattery(agalvanic cell) that is designed to be used once and discarded, and it is not rechargeable unlike a secondary cell (rechargeable battery). In general, theelectrochemicalreactionoccurring in the cell is not reversible, rendering the cell unrechargeable. As a primary cell is used,chemical reactionsin the battery use up the chemicals that generate the power; when they are gone, the battery stops producing electricity. In contrast, in asecondary cell,the reaction can be reversed by running a current into the cell with abattery chargerto recharge it, regenerating the chemical reactants. Primary cells are made in a range of standard sizes to power small household appliances such asflashlightsand portable radios.
Primary batteries make up about 90% of the $50 billion battery market, but secondary batteries have been gaining market share. About 15 billion primary batteries are thrown away worldwide every year, virtually all ending up in landfills. Due to the toxicheavy metalsand strong acids and alkalis they contain, batteries arehazardous waste.Most municipalities classify them as such and require separate disposal. The energy needed to manufacture a battery is about 50 times greater than the energy it contains.[1][2][3][4]Due to their high pollutant content compared to their small energy content, the primary battery is considered a wasteful, environmentally unfriendly technology. Due mainly to increasing sales ofwireless devicesandcordless toolswhich cannot be economically powered by primary batteries and come with integral rechargeable batteries, the secondary battery industry has high growth and has slowly been replacing the primary battery in high end products.
Usage trend
editIn the early twenty-first century, primary cells began losing market share to secondary cells, as relative costs declined for the latter. Flashlight power demands were reduced by the switch fromincandescent bulbstolight-emitting diodes.[5]
The remaining market experienced increased competition from private- or no-label versions. The market share of the two leading US manufacturers, Energizer and Duracell, declined to 37% in 2012. Along with Rayovac, these three are trying to move consumers fromzinc–carbonto more expensive, longer-lastingalkaline batteries.[5]
Western battery manufacturers shifted production offshore and no longer make zinc-carbon batteries in the United States.[5]
China became the largest battery market, with demand projected to climb faster than anywhere else, and has also shifted to alkaline cells. In other developing countries disposable batteries must compete with cheap wind-up, wind-powered and rechargeable devices that have proliferated.[5]
Comparison between primary and secondary cells
editSecondary cells (rechargeable batteries) are in general more economical to use than primary cells. Their initially higher cost and the purchase cost of a charging system can be spread out over many use cycles (between 100 and 1000 cycles); for example, in hand-held power tools, it would be very costly to replace a high-capacity primary battery pack every few hours of use.
Primary cells are not designed for recharging between manufacturing and use, thus have battery chemistry that has to have a much lower self-discharge rate than older types of secondary cells; but they have lost that advantage with the development of rechargeable secondary cells with very lowself-dischargerates like low self-discharge NiMH cells that hold enough charge for long enough to be sold as pre-charged.[6][7]
Common types of secondary cells (namely NiMH and Li-ion) due to their much lowerinternal resistancedo not suffer the large loss of capacity that alkaline, zinc–carbon and zinc chloride ( "heavy duty" or "super heavy duty" ) do with high current draw.[8]
Reserve batteriesachieve very long storage time (on the order of 10 years or more) without loss of capacity, by physically separating the components of the battery and only assembling them at the time of use. Such constructions are expensive but are found in applications likemunitions,which may be stored for years before use.
Polarization
editA major factor reducing the lifetime of primary cells is that they becomepolarizedduring use. This means thathydrogenaccumulates at the cathode and reduces the effectiveness of the cell. To reduce the effects of polarization in commercial cells and to extend their lives, chemical depolarization is used; that is, anoxidizing agentis added to the cell, to oxidize the hydrogen to water.Manganese dioxideis used in theLeclanché cellandzinc–carbon cell,andnitric acidis used in theBunsen cellandGrove cell.
Attempts have been made to make simple cells self-depolarizing by roughening the surface of the copper plate to facilitate the detachment of hydrogen bubbles with little success. Electrochemical depolarization exchanges the hydrogen for a metal, such ascopper(e.g.Daniell cell), orsilver(e.g.silver-oxide cell), so called.
Terminology
editAnode and cathode
editThe battery terminal (electrode) that develops a positive voltage polarity (thecarbonelectrode in a dry cell) is called thecathodeand the electrode with a negative polarity (zincin a dry cell) is called theanode.[9]This is thereverseof the terminology used in anelectrolytic cellorthermionicvacuum tube.The reason is that the terms anode and cathode are defined by the direction of electric current, not by their voltage. The anode is the terminal through whichconventional current(positive charge) enters the cell from the external circuit, while the cathode is the terminal through which conventional current leaves the cell and flows into the external circuit. Since a battery is a power source which provides the voltage which forces the current through the external circuit, the voltage on the cathode must be higher than the voltage on the anode, creating an electric field directed from cathode to anode, to force the positive charge out of the cathode through the resistance of the external circuit.
Inside the cell the anode is the electrode where chemicaloxidationoccurs, as it donates electrons which flow out of it into the external circuit. The cathode is the electrode where chemicalreductionoccurs, as it accepts electrons from the circuit.
Outside the cell, different terminology is used. As the anode donates positive charge to the electrolyte (thus remaining with an excess of electrons that it will donate to the circuit), it becomes negativelychargedand is therefore connected to the terminal marked "−" on the outside of the cell. The cathode, meanwhile, donates negative charge to the electrolyte, so it becomes positively charged (which allows it to accept electrons from the circuit) and is therefore connected to the terminal marked "+" on the outside of the cell.[10]
Old textbooks sometimes contain different terminology that can cause confusion to modern readers. For example, a 1911 textbook by Ayrton and Mather[11]describes the electrodes as the "positive plate" and "negative plate".
See also
editReferences
edit- ^Hill, Marquita K. (2004).Understanding Environmental Pollution: A Primer.Cambridge University Press. pp.274.ISBN0521527260.
battery energy 50 times environment pollution.
- ^Watts, John (2006).Gcse Edexcel Science.Letts and Lonsdale. p. 63.ISBN1905129637.
- ^Wastebusters (2013).The Green Office Manual: A Guide to Responsible Practice.Routledge. p. 96.ISBN978-1134197989.
- ^Danaher, Kevin; Biggs, Shannon; Mark, Jason (2016).Building the Green Economy: Success Stories from the Grassroots.Routledge. p. 199.ISBN978-1317262923.
- ^abcd"Batteries: Out of juice".The Economist.2014-01-18.Retrieved2014-02-10.
- ^"Eneloop AA 4-Pack".
- ^"Eneloop Self Discharge study".22 January 2007.
- ^"Discharge tests of Alkaline AA batteries".
- ^Denker, John S. (2004)."How to Define Anode and Cathode".See How It Flies.Denker personal website.Retrieved8 September2018.
- ^John S. Newman, Karen E. Thomas-Alyea,Electrochemical systems,Wiley-IEEE, 3rd ed. 2004,ISBN0-471-47756-7
- ^W. E. Ayrton and T. Mather,Practical Electricity,Cassell and Company, London, 1911, page 170
External links
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