Jump to content

Boehmite

From Wikipedia, the free encyclopedia
Boehmite
Böhmite andNatrolitefrom Sagåsen (Strandåsen), Mørje, Porsgrunn, Telemark, Norway (Field of view 10 mm)
General
CategoryOxide mineral
Formula
(repeating unit)
γ-AlO(OH)
IMA symbolBhm[1]
Strunz classification4.FE.15
Dana classification6.1.2.1
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol:(2/m 2/m 2/m)
Space groupAmam
Unit cella = 3.693Å,
b = 12.221 Å,
c = 2.865 Å; Z = 4
Identification
ColorWhite, pale greyish brown; yellowish or reddish when impure; colorless in thin section
Crystal habitTabular crystal rare, fine grained in pisolitic aggregates or disseminated
CleavageVery good on {010}, good on {100}, and poor on {001}
FractureUneven
TenacityBrittle
Mohs scalehardness3.5
LusterVitreous, pearly on {010}
StreakWhite
DiaphaneityTranslucent
Specific gravity3.02–3.05
Optical propertiesBiaxial (+)
Refractive indexnα= 1.644 – 1.648 nβ= 1.654 – 1.657 nγ= 1.661 – 1.668
Birefringenceδ = 0.017 – 0.020
2V angleMeasured: 74° to 88°, Calculated: 80°
Dispersionweak
References[2][3][4][5]

Boehmiteorböhmiteis analuminium oxide hydroxide(γ-AlO(OH)) mineral, a component of thealuminiumorebauxite.It isdimorphouswithdiaspore.It crystallizes in theorthorhombicdipyramidal system and is typically massive in habit. It is white with tints of yellow, green, brown or red due to impurities. It has a vitreous to pearly luster, aMohs hardnessof 3 to 3.5 and aspecific gravityof 3.00 to 3.07. It is colorless in thin section, optically biaxial positive withrefractive indicesof nα = 1.644 – 1.648, nβ = 1.654 – 1.657 and nγ = 1.661 – 1.668.

Boehmite occurs in tropicallateritesand bauxites developed onalumino-silicatebedrock. It also occurs as ahydrothermal alterationproduct ofcorundumandnepheline.It occurs withkaolinite,gibbsiteand diaspore in bauxite deposits; and with nepheline, gibbsite, diaspore,natroliteandanalcimein nephelinepegmatites.[4]Industrially, it is used as an inexpensiveflame retardantadditive forfire-safe polymers.

It was first described by J. de Lapparent in 1927 for an occurrence in the bauxites of Mas Rouge,Les Baux-de-Provence,France,and named[6]for the Bohemian-German chemistJohann Böhm(1895–1952) who carried out X-ray studies of aluminium oxide hydroxides in 1925[7](and not for the German geologistJohannes Böhm(1857–1938) as often stated).[2][3]

See also[edit]

References[edit]

  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85(3): 291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID235729616.
  2. ^ab"Boehmite".Webmineral data.Retrieved2010-07-10.
  3. ^ab"Boehmite".Mindat with location data.Retrieved2010-07-10.
  4. ^abMineral Data Pub. Handbook of Mineralogy
  5. ^"The Mineral Boehmite".minerals.net.RetrievedJune 10,2014.
  6. ^Sahama, Th. G.; Lehtinen, Martti; Rehtijärvi, Pentti (1973). "Natural boehmite single crystals from Ceylon".Contributions to Mineralogy and Petrology.39(2): 171.Bibcode:1973CoMP...39..171S.doi:10.1007/BF00375738.S2CID129237343.
  7. ^Böhm, J. (1925). "Über Aluminium- und Eisenhydroxyde. I".Zeitschrift für anorganische und allgemeine Chemie.149:203–216.doi:10.1002/zaac.19251490114.