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Diaspore

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Diaspore
General
CategoryOxide mineral
Formula
(repeating unit)
α-AlO(OH)
IMA symbolDsp[1]
Strunz classification4.FD.10
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H–M symbol:(2/m 2/m 2/m)
Space groupPbnm
Unit cella= 4.4007(6)Å
b= 9.4253(13) Å
c= 2.8452(3) Å;Z= 4
Identification
ColorWhite, pale gray, colorless, greenish gray, brown, pale yellow, pink, purple; may exhibit color change
Crystal habitPlaty, elongated toacicularcrystals; also stalactitic, foliated, scaly, disseminated, and massive
TwinningForms heart shaped twins on {021} or pseudohexagonal aggregates
Cleavage{010} perfect, {110} distinct, {100} in traces
FractureConchoidal
TenacityVery brittle
Mohs scalehardness6.5–7.0
LusterAdamantine, vitreous, pearly on cleavage faces
DiaphaneityTransparent to translucent
Specific gravity3.1–3.4
Optical propertiesBiaxial (+)
Refractive indexnα= 1.682–1.706
nβ= 1.705–1.725
nγ= 1.730–1.752
Birefringenceδ= 0.048
PleochroismStrong
2V angleMeasured: 84–86°
Calculated: 80–84°
Dispersionr<v,weak
FusibilityInfusible
SolubilityInsoluble
Other characteristicsDecrepitates releasing water in closed tube on heating
References[2][3]

Diaspore(/ˈd.əˌspɔːr/) – also calleddiasporite,empholite,kayserite,ortanatarite– is analuminium hydroxide oxidemineral, α-AlO(OH), crystallizing in theorthorhombicsystem andisomorphouswithgoethite.It occurs sometimes as flattened crystals, but usually as lamellar or scaly masses, the flattened surface being a direction of perfectcleavageon which thelustreis markedly pearly in character. It is colorless or greyish-white, yellowish, sometimes violet in color, and varies fromtranslucent to transparent.[4]It may be readily distinguished from other colorless transparent minerals with a perfect cleavage and pearly luster (e.g.mica,talc,brucite,andgypsum) by its greater hardness of 6.5–7. Itsspecific gravityis 3.4. When heated before the blowpipe, itdecrepitatesviolently, breaking up into white pearly scales.[5]

The mineral occurs as an alteration product ofcorundumoremeryand is found in granularlimestoneand other crystalline rocks. Well-developed crystals are found in the emery deposits of theUral Mountainsand atChester, Massachusetts,and inkaolinat Schemnitz inHungary.If obtainable in large quantity, it would be of economic importance as a source ofaluminium.[5]

Diaspore, along withgibbsiteandboehmite,is a major component of the aluminiumorebauxite.[3]

It was first described in 1801 for an occurrence in Mramorsk Zavod,Sverdlovskaya Oblast,MiddleUrals,Russia.The name, which was coined byRené Just Haüy,[6]is from theAncient Greekδιασπείρωmeaning "to scatter", in allusion to its decrepitation on heating.[2]

Csarite,ottomanite,Turkiziteandzultaniteare trade names for gem-quality diaspore (also known as Turkish diaspore) from theİlbir Mountainsof southwestTurkey.[7]

References[edit]

  1. ^Warr, L. N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85(3): 291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID235729616.
  2. ^abHandbook of Mineralogy
  3. ^abKlein, Cornelis; Hurlbut, Cornelius S. (1985).Manual of Mineralogy(20th ed.).Wiley.p. 318.ISBN0-471-80580-7.
  4. ^"The mineral diaspore".minerals.net.Retrieved2014-06-10.
  5. ^abOne or more of the preceding sentences incorporates text from a publication now in thepublic domain:Spencer, Leonard James(1911). "Diaspore".InChisholm, Hugh(ed.).Encyclopædia Britannica.Vol. 8 (11th ed.). Cambridge University Press. pp. 168–169.
  6. ^Spencer 1911.
  7. ^Hatipoğlu, Murat; Türk, Necdet; Chamberlain, Steven C.; Akgün, A. Murat (2010). "Gem-quality transparent diaspore (zultanite) in bauxite deposits of the İlbir Mountains, Menderes Massif, SW Turkey".Mineralium Deposita.45(2): 201–205.doi:10.1007/s00126-009-0262-2.