Geikielite
Appearance
Geikielite | |
---|---|
![]() Crystals of geikielite from the Maxwell quarry, Chelsea, Outaouais, Québec, Canada | |
General | |
Category | Oxide mineral |
Formula (repeating unit) | MgTiO3 |
IMA symbol | Gk[1] |
Strunz classification | 4.CB.05 |
Crystal system | Trigonal |
Crystal class | Rhombohedral (3) (sameH-M symbol) |
Space group | R3 |
Unit cell | a = 5.05478(26) Å c = 13.8992(7) Å; Z = 6 |
Identification | |
Color | Black, ruby red uncommon; red internal reflections |
Crystal habit | Tabular prismatic crystals, also as finely granular masses |
Cleavage | Good on {1011} |
Mohs scalehardness | 5 - 6 |
Luster | Sub-metallic |
Streak | Purplish brown |
Diaphaneity | Opaque to translucent |
Specific gravity | 3.79 - 4.2 |
Optical properties | Uniaxial (-) |
Refractive index | nω= 2.310 - 2.350 nε= 1.950 - 1.980 |
Birefringence | δ = 0.360 - 0.370 |
Pleochroism | Weak, O = pinkish red, E = brownish to purplish red |
References | [2][3][4] |
Geikieliteis a magnesium titaniumoxide mineralwith formula: MgTiO3.It is a member of theilmenitegroup. It crystallizes in thetrigonalsystem forming typically opaque, black to reddish black crystals.
It was first described in 1892[5]for an occurrence in the Ceylonese gem bearing gravelplacers.It was named for Scottish geologistSir Archibald Geikie(1835–1924).[4]It occurs inmetamorphosedimpure magnesianlimestones,inserpentinitederived fromultramafic rocks,inkimberlitesandcarbonatites.Associated minerals includerutile,spinel,clinohumite,perovskite,diopside,serpentine,forsterite,brucite,hydrotalcite,chloriteandcalcite.[2]
References[edit]
- ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85(3): 291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID235729616.
- ^abHandbook of Mineralogy
- ^Geikielite on Mindat.org
- ^abGeikielite on Webmineral
- ^Fletcher, L. (1892)."Geikielite and Baddeleyite, Two New Mineral Species".Nature.46(1200): 620–621.Bibcode:1892Natur..46..620F.doi:10.1038/046620b0.
Further reading[edit]
- Ghiorso, Mark S.(1990). "Thermodynamic properties of hematite — Ilmenite — Geikielite solid solutions".Contributions to Mineralogy and Petrology.104(6): 645–667.Bibcode:1990CoMP..104..645G.doi:10.1007/BF01167285.S2CID98522254.
- Reynard, B.; Guyot, F. (1994). "High-temperature properties of geikielite (MgTiO3-ilmenite) from high-temperature high-pressure Raman spectroscopy? Some implications for MgSiO3-ilmenite ".Physics and Chemistry of Minerals.21(7): 441.Bibcode:1994PCM....21..441R.doi:10.1007/BF00202274.S2CID96095190.
- Baura-Peña, M. P.; Martínez-Lope, M. J.; García-Clavel, M. E. (1991). "Synthesis of the mineral geikielite MgTiO3".Journal of Materials Science.26(16): 4341.Bibcode:1991JMatS..26.4341B.doi:10.1007/BF00543648.S2CID94170430.
- Robie, Richard A.; Haselton, H.T.; Hemingway, Bruce S. (1989)."Heat capacities and entropies at 298.15 K of MgTiO3(geikielite), ZnO (zincite), and ZnCO3(smithsonite) ".The Journal of Chemical Thermodynamics.21(7): 743.doi:10.1016/0021-9614(89)90058-X.
- Gieré, Reto (1987)."Titanian clinohumite and geikielite in marbles from the Bergell contact aureole".Contributions to Mineralogy and Petrology.96(4): 496–502.Bibcode:1987CoMP...96..496G.doi:10.1007/BF01166694.S2CID86861792.
- Parthasarathy, G. (2007). "Electrical resistivity of nano-crystalline and natural MgTiO3−geikielite at high-pressures up to 8 GPa ".Materials Letters.61(21): 4329–4331.doi:10.1016/j.matlet.2007.01.097.
- Mitchell, Jeremy N.; Yu, Ning; Sickafus, Kurt E.; Nastasi, Michael A.; McClellan, Kenneth J. (1998). "Ion irradiation damage in geikielite (MgTiO3) ".Philosophical Magazine A.78(3): 713.Bibcode:1998PMagA..78..713M.doi:10.1080/01418619808241931.
- Chao, G. Y.; Hounslow, A. W. (June 1967)."Geikielite; a new Canadian occurrence".The Canadian Mineralogist.9(1): 95–100.