Jump to content

Nitride chloride

Add links
From Wikipedia, the free encyclopedia

Achloride nitrideis amixed anion compoundcontaining bothchloride(Cl−) andnitrideions (N3−). Another name ismetallochloronitrides.They are a subclass of halide nitrides orpnictide halides.[1]

Thegroup 4 elementchloride nitrides can be intercalated by alkali metals that supply extra electrons, and other molecules such as from solvents liketetrahydrofuran,yielding layered substances that aresuperconductors.A superconductor transition temperatureTcof 25.5K has been achieved.[2]

Production

[edit]

Nitride chlorides may be produced by heating metal nitrides with metal chlorides. The ammonolysis process heats a metal chloride withammonia.[3]A related method heats a metal or metal hydride withammonium chloride.The nitrogen source could also be anazideor an amide.[3]

List

[edit]
name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225c=1977.18 Z=3 [4]
Li1.8N0.4Cl0.6 Liion conductor [5]
Cyanogen chloride ClCN molecular
Magnesium nitride chloride Mg2NCl hexagonal R3m a= 3.2994c= 17.857 [6]
phosphonitrilic chloride cyclic trimer P3N3Cl6 molecular
trithiazyl trichloride S3N3Cl3 cas 5964-00-1 [7]
Ca2NCl hexagonal R3m a3.6665c19.7187 [8]
Sc2Cl2N P3m1 a = 3:517 c = 8.813 layered [1]
Sc4Cl6N orthorhombic Pbam a = 11.625, b = 12.118, c = 3.5447 [1]
Sc5Cl8N C2/m a = 17.85, b = 3.5505, c = 12.090, β = 130.13 [1]
Sc7Cl12N R3 a = 12.990, c = 8.835 Sc6N clusters [1]
Titanium nitride chloride TiNCl orthorhombic Pmmn a=3.275 b=3.967 c=8.402

a = 3.937, b = 3.258, c = 7.803

109.2 black [9]
Li0.6TiNCl [9]
Cl3VNCl triclinic P1 a = 7.64, b = 7.14, c = 5.91, α = 94.9, β = 112.4, γ = 107.8 V=NClcomplex [1]
Zn2NCl 180.20 orthorhombic Pna21 a=6.137 b=7.394 c=5.940 Z=4 269.5 4.441 band gap 3.21 eV [10]
Zn2NCl orthorhombic Pnma Z=16 predicted [11]
Zn2NCl hexagonal R3m predicted [11]
Sr2BN2Cl [12]
α-Y2Cl3N orthorhombic Pbcn a = 12.761, b = 6.676, c = 6.1000 [1]
β-Y2Cl3N C2/m a = 15.248, b = 3.8520, c = 10.157, β = 118.41 [1]
α-ZrNCl orthorhombic Pmmn a = 3.937, b = 3.258, c = 7.803 pale yellow-green [1]
β-zirconium nitride chloride β-ZrNCl hexagonal R3m a = 3.6031, c = 27.672 yellow-green;semiconductor;layers of Cl–Zr–N–N–Zr–Cl [13][1]
Zr6Cl15N cubic Ia3d a = 21.171 [1]
Lithium-intercalated β-zirconium nitride chloride LixZrNCl black;superconductorTc=12.5 K [14]
NaxZrNCl superconductorTc15 K [13]
KxZrNCl superconductorTc15 K [13]
molybdenum nitride chloride MoNCl3 triclinic P1 a = 9.14, b = 7.67, c = 8.15, α = 108.8, β = 99.3, γ= 108.6 [15][1]
Mo2NCl7 triclinic P1 a = 9.057, b = 9.754, c = 12.834, α = 103.13, β = 109.83, γ = 98.58 [1]
Mo2NCl8 monoclinic P2/c a = 9.961, b = 6.294, c = 17.808, β = 101.82 [1]
Phenyldiazonium tetrachloronitridomolybdate C6H5N2[MoNCl4] monoclinic P21/c a = 12.83, b = 11.70, c = 19.22 β = 94.11 Z=2 dark red [15]
Technetium chloride nitride TcCl3N black; cas 154525-32-3 [7]
(Ph4As)[TcNCl4] [16]
[Se3N2Cl]+SbCl6- triclinic P1 a=6.982 b=6.997 c=15.105 α = 89.45°, β = 86.18°, γ = 68.22° Z=2 red [17]
Ba2NCl hexagonal R3m
Ba3Si3N5OCl P62c a=9.560c=5.552 [18]
Ba25Nb5N19Cl18 [1]
LiBa4[Mo2N7]BaCl2 [1]
La2NCl3 orthorhombic Ibam a= 13.758,b= 6.922,c= 6.185 [19]
La2Cl(CN2)N orthorhombic Cmmm a= 13.340,b= 9.5267,c= 3.9402, Z=4 [20]
La6N3S4Cl orthorhombic Pnma a = 11.597; b = 4.1095; c = 27.568 Z=4 [21]
CeNCl tetragonal P4/nmm a=4.079 c=6.837 Z= black [22]
Cerium(III) nitride chloride Ce2NCl3 orthorhombic Ibam a= 13.6021 b=6.8903 c= 6.1396 Z=4 575.42 4.624 Light yellow [23]
Ce2Cl(CN2)N orthorhombic Cmmm a= 13.3914,b= 9.6345,c= 3.9568, Z=4 [20]
Ce6Cl12N2 1294.1 monoclinic P21/c a=11.233 b=16.527 c=10.798β=90.15 Z=4 1988 4.324 yellow [22]
Na2[{(ON)Ce4}Cl9] monoclinic P21/m a= 8.1321,b= 11.4613,c= 9.4286 andβ= 107.504° Z=2 [24]
Pr2NCl3 orthorhombic Ibam a= 13.531,b= 6.8512,c= 6.1072 [19]
Pr5N3S2Cl2 monoclinic C2/m a = 15.402; b = 4.0092; c = 16.563; β = 101.24°, Z = 4 [25]
Pr6N3S4Cl orthorhombic Pnma a=11.3987 b=4.0235 c=26.999 Z=4 1238.3 reddish-brown [26]
Nd2NCl3 orthorhombic Pbcn a= 13.382,b= 6.8462,c= 6.1815 [19]
Nd3NCl6 orthorhombic Pbca a = 10.4971, b = 11.0683, c = 16.211; Z = 8 [27]
Nd4NS3Cl3 hexagonal P63mc a = 9.2278, c = 6.8306; Z = 2 [27]
Nd6N3S4Cl orthorhombic Pnma a = 11.371; b = 3.9934; c = 26.876 [21]
Na2Nd4ONCl9 monoclinic P21/m a= 8.0354,b= 11.3426,c= 9.2831 andβ= 107.109° [28]
Trigadolinium hexachloride nitride Gd3Cl6N 698.485 triclinic P1 a = 7.107, b = 8.156, c = 9.707, α = 75.37°, β = 109.10°, γ = 114.64° Z=2 478.8 4.84 colourless; water sensitive;biaxial(−) [29]
Gd2NCl3 orthorhombic Pbcn a=13.017 b=6.7310 c=6.1403 [19]
Gd2N2Cl tetragonal P4mm a = 4.25 c = 5.92 [30]
α-HfNCl orthorhombic Pmmn a = 4.130, b = 3.497, c = 8.070 [31][1]
β-HfNCl hexagonal R3m a = 3.5744, c = 27.7075 colourless [1]
NaxHfNCl superconductorTc25 K [32]
Ba3Ta3N6Cl P62c a=10.1455c=5.9770 [18]
Ba3Cl2TaN3 hexagonal P63cm a= 15.0739,c= 6.3298;Z= 6 light yellow [33]
Ba15Ta15N33Cl4 P62c a=10.1545c=29.917 [18]
W2NCl8 triclinic P1 a = 6.2423, b = 6.309, c = 6.931, α = 89.76, β = 81.51, γ = 82.68 [1]
W2NCl9 P21/c a = 8.421, b = 16.786, c = 11.930, β = 134.74° [1]
[WNCl3• POCl3]4• 2 POCl3 triclinic P1 a = 12.257 b = 11.851 c = 19.27.0 α = 102.6° β= 108.4°γ= 94.8° Z=2 [34]
Ba4[WN4]Cl2 [1]
ReNCl4 tetragonal I4 a=8.278 b=8.281 c=4.057 Z=2 brown [35][36]
ReNCl4·H2O orthorhombic Pnma a = 10.754, b = 11.085, c = 547.7 Z=4 red [36]
[NBu4][ReNCl4] orthorhombic P4/n a11.795b11.795c8.466 ReNtriple bondin complex [37]
K2OsNCl5 orthorhombic Pnma a = 13.27, b = 9.85, c = 6.84 [1]
Kleinite Hg2N(Cl,SO4)•n(H2O) hexagonal C63/mmc a = 13.56 c = 11.13 Z = 18 1,772.33 8.01 yellow [38]
Mosesite Hg2N(Cl,SO4,MoO4,CO3)•(H2O) cubic F43m a = 9.524, Z = 8 863.89 7.71 yellow; refractive index 2.065 [39]
ThNCl tetragonal P4/nmm a=4.09486c=6.9013 [40]
Uranium nitride chloride UNCl tetragonal P4/nmm a=3.97 c=6.81 Z=2 [41]

References

[edit]
  1. ^abcdefghijklmnopqrstuvHeadspith, David A.; Francesconi, M. Grazia (October 2009)."Transition Metal Pnictide-Halides: A Class of Under-Explored Compounds".Topics in Catalysis.52(11): 1611–1627.doi:10.1007/s11244-009-9282-5.ISSN1022-5528.S2CID93522549.
  2. ^Yamanaka, Shoji (2010)."Intercalation and superconductivity in ternary layer structured metal nitride halides (MNX: M = Ti, Zr, Hf; X = Cl, Br, I)".Journal of Materials Chemistry.20(15): 2922.doi:10.1039/b922149b.ISSN0959-9428.
  3. ^abSchurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011)."Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)".Zeitschrift für Kristallographie.226(4): 395.Bibcode:2011ZK....226..395S.doi:10.1524/zkri.2011.1350.ISSN0044-2968.S2CID93973409.
  4. ^Marx, Rupert (February 1997)."Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl".Journal of Solid State Chemistry.128(2): 241–246.Bibcode:1997JSSCh.128..241M.doi:10.1006/jssc.1996.7196.
  5. ^Hartwig, P.; Weppner, W.; Wichelhaus, W. (April 1979)."Fast ionic lithium conduction in solid lithium nitride chloride".Materials Research Bulletin.14(4): 493–498.doi:10.1016/0025-5408(79)90191-0.
  6. ^Li, Yanqing; George, Janine; Liu, Xiaohui; Dronskowski, Richard (February 2015)."Synthesis, Structure Determination and Electronic Structure of Magnesium Nitride Chloride, Mg 2 NCl: Magnesium Nitride Chloride, Mg 2 NCl".Zeitschrift für anorganische und allgemeine Chemie.641(2): 266–269.doi:10.1002/zaac.201400496.
  7. ^abMacintyre, Jane E. (1995-10-12).Dictionary of Inorganic Compounds, Supplement 3.CRC Press. p. 274.ISBN978-0-412-49110-8.
  8. ^Bowman, Amy; Smith, Ronald I.; Gregory, Duncan H. (June 2005)."Ternary and quaternary layered nitride halides, Ca2N(X,X′) (X,X′=Cl, Br, I): Evolution of structure with composition".Journal of Solid State Chemistry.178(6): 1807–1817.Bibcode:2005JSSCh.178.1807B.doi:10.1016/j.jssc.2005.03.021.
  9. ^abKuhn, A.; Hoppe, H.; Strähle, J.; Garcı́a-Alvarado, F. (2004)."Electrochemical Lithium Intercalation in Titanium Nitride Chloride".Journal of the Electrochemical Society.151(6): A843.Bibcode:2004JElS..151A.843K.doi:10.1149/1.1740782.
  10. ^Zhao, Xin; Lin, Chensheng; Chen, Jindong; Luo, Min; Xu, Feng; Yang, Shunda; Shi, Shuangshuang; Li, Bingxuan; Ye, Ning (2021-02-23)."Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials".Chemistry of Materials.33(4): 1462–1470.doi:10.1021/acs.chemmater.0c04772.ISSN0897-4756.S2CID234068556.
  11. ^abLi, Xiaofeng; Tao, Yaping; Lv, Jian; Hu, Ziyu; Liu, Zhong-Li (August 2015)."Pressure-induced phase transition of zinc nitride chlorine".Computational Materials Science.106:175–179.doi:10.1016/j.commatsci.2015.04.043.
  12. ^Wang, Haoyang; Li, Zebin; Kang, Runtian; Ji, Ruijie; Wang, Yuhua (2022-11-14)."Sr 2 BN 2 Cl:Eu 2+ -Based Narrow-Band Blue-Emitting Phosphor: A Potential Color Converter for Illumination and Displays".Inorganic Chemistry.61(45): 18245–18252.doi:10.1021/acs.inorgchem.2c03069.ISSN0020-1669.PMID36373304.S2CID253309150.
  13. ^abcKawaji, Hitoshi; Hotehama, Ken-ichi; Yamanaka, Shoji (1997-10-01)."Superconductivity of Alkali Metal Intercalated β-Zirconium Nitride Chloride, A x ZrNCl (A = Li, Na, K)".Chemistry of Materials.9(10): 2127–2130.doi:10.1021/cm970211b.ISSN0897-4756.
  14. ^Yamanaka, Shoji; Kawaji, Hitoshi; Hotehama, Ken-ichi; Ohashi, Masao (September 1996)."A new layer-structured nitride superconductor. Lithium-intercalated?-zirconium nitride chloride, LixZrNCl".Advanced Materials.8(9): 771–774.doi:10.1002/adma.19960080917.ISSN0935-9648.
  15. ^abMueller, U.; Kujanek, R.; Dehnicke, K. (1982)."Molybdenum-nitride-trichloride-di-n-butylether [MoNCl3. O(C4H9)2]4; preparation, i.r. spectrum, and crystal structure".Zeitschrift für anorganische und allgemeine Chemie(in German).495:127–134.ISSN0044-2313.
  16. ^Abram, U.; Wollert, R. (1993)."The synthesis of TcNCl3; new approaches to TcNCl-4".Radiochimica Acta.63:149–151.doi:10.1524/ract.1993.63.special-issue.149.ISSN0033-8230.S2CID99730801.
  17. ^Lau, Carsten; Neumüller, Bernhard; Dehnicke, Kurt (1997-04-01)."Synthese und Kristallstruktur von [Se 3 N 2 Cl] + SbCl 6 - / Synthesis and Crystal Structure of [Se 3 N 2 Cl] + SbCl 6 -".Zeitschrift für Naturforschung B.52(4): 543–545.doi:10.1515/znb-1997-0416.ISSN1865-7117.S2CID101616974.
  18. ^abcBarnes, Andrew J. D.; Prior, Timothy J.; Francesconi, M. Grazia (2007)."Zeolite-like nitride–chlorides with a predicted topology".Chemical Communications(44): 4638–4640.doi:10.1039/b712110e.ISSN1359-7345.PMID17989817.
  19. ^abcdUhrlandt, Stefan; Meyer, Gerd (July 1995)."Nitride chlorides of the early lanthanides: [M2N]Cl3(M=LaNd)".Journal of Alloys and Compounds.225(1–2): 171–173.doi:10.1016/0925-8388(94)07028-8.
  20. ^abSrinivasan, Radhakrishnan; Ströbele, Markus; Meyer, H.-Jürgen (2003-06-01)."Chains of [RE 6 ] Octahedra Coupled by (NCN) Links in the Network Structure of RE 2 Cl(CN 2 )N. Synthesis and Structure of Two Novel Rare Earth Chloride Carbodiimide Nitrides with Structures Related to the RE 2 Cl 3 Type".Inorganic Chemistry.42(11): 3406–3411.doi:10.1021/ic020685z.ISSN0020-1669.PMID12767174.
  21. ^abLissner, Falk; Schleid, Thomas; Meyer, Monika (February 1996)."Nitridsulfidchloride der Lanthanide: II. Der Formeltyp M6N3S4Cl (M = La?Nd)".Zeitschrift für anorganische und allgemeine Chemie(in German).622(2): 275–282.doi:10.1002/zaac.19966220213.ISSN0044-2313.
  22. ^abEhrlich, Grant M.; Badding, M.E.; Brese, Nathaniel E.; Trail, Steven S.; DiSalvo, F.J. (April 1994)."New cerium nitride chlorides: Ce6Cl12N2 and CeNCl".Journal of Alloys and Compounds.206(1): 95–101.doi:10.1016/0925-8388(94)90015-9.
  23. ^Schurz, Christian M.; Schleid, Thomas (2011-07-15)."A-type Ce 2 NCl 3".Acta Crystallographica Section E.67(7): i42.doi:10.1107/S1600536811023105.ISSN1600-5368.PMC3151823.PMID21836827.
  24. ^Schurz, Christian M.; Meyer, Monika; Meyer, Gerd; Schleid, Thomas (2010-05-25)."A New Example of the Structure Type A2[{Z2R4}X9]: Synthesis and Crystal Structure of Na2[{(ON)Ce4}Cl9]".Zeitschrift für anorganische und allgemeine Chemie.636(7): 1169–1171.doi:10.1002/zaac.201000111.
  25. ^Lissner, Falk; Schleid, Thomas (November 1997)."Nitridsulfidchloride der Lanthanide: III. Synthese und Kristallstruktur von Pr5N3S2Cl2".Zeitschrift für anorganische und allgemeine Chemie(in German).623(11): 1747–1752.doi:10.1002/zaac.19976231114.ISSN0044-2313.
  26. ^Meyer, M.; Schleid, Th. (1999-03-01)."Crystal structure of hexapraseodymium(III) trinitride tetrasulfide chloride, Pr6N3S4Cl".Zeitschrift für Kristallographie – New Crystal Structures.214(1): 23–24.doi:10.1515/ncrs-1999-0116.ISSN2197-4578.S2CID95080228.
  27. ^abMeyer, Monika; Lissner, Falk; Schleid, Thomas (2000)."Nd3NCl6 und Nd4NS3Cl3: Zwei Neodymnitrid-Derivate mit diskreten Einheiten kantenverknüpfter ([N2Nd6]12+) bzw. isolierter [NNd4]9+-Tetraeder".Zeitschrift für anorganische und allgemeine Chemie(in German).626(5): 1205–1210.doi:10.1002/(SICI)1521-3749(200005)626:5<1205::AID-ZAAC1205>3.0.CO;2-T.ISSN1521-3749.
  28. ^Schurz, Christian M.; Schleid, Thomas (October 2009)."Chains of trans-edge connected [ZM4] tetrahedra (Z=N and O) in the lanthanide nitride chlorides M2NCl3 and Na2M4ONCl9 (M=La–Nd)".Journal of Alloys and Compounds.485(1–2): 110–118.doi:10.1016/j.jallcom.2009.06.097.
  29. ^Simon, A.; Koehler, T. (February 1986). "A new gadolinium nitride chloride—Gd3Cl6N".Journal of the Less Common Metals.116(1): 279–292.doi:10.1016/0022-5088(86)90236-5.
  30. ^Chen, Ning; Liu, Xiuxia; Liu, Yang; Li, Yang (March 2013)."Study on novel rare-earth nitride chlorides GdNCl and Gd2N2Cl".APS March Meeting Abstracts.2013:Q1.299.Bibcode:2013APS..MAR.Q1299C.
  31. ^Felser, Claudia; Seshadri, Ram (1999)."Electronic structures and instabilities of ZrNCl and HfNCl: implications for superconductivity in the doped compounds".Journal of Materials Chemistry.9(2): 459–464.doi:10.1039/a808127a.
  32. ^Weht, R.; Filippetti, A.; Pickett, W. E. (1999-11-01)."Electron doping in the honeycomb bilayer superconductors (Zr, Hf)NCl".EPL (Europhysics Letters).48(3): 320.Bibcode:1999EL.....48..320W.doi:10.1209/epl/i1999-00484-4.ISSN0295-5075.S2CID250844908.
  33. ^Blaschkowski, Björn; Dürr, Oliver; Reckeweg, Olaf; Schleid, Thomas (July 2015)."Crystal Growth and Structure of the Barium Chloride Nitridotantalate(V) Ba 3 Cl 2 TaN 3".Zeitschrift für anorganische und allgemeine Chemie.641(8–9): 1515–1520.doi:10.1002/zaac.201500201.
  34. ^Musterle, Wilfried; Strähle, Joachim; Liebelt, Wolfgang; Dehnicke, Kurt (1979-07-01)."Darstellung, IR-Spektrum und Kristallstruktur von [WNCI 3 P0Cl 3 ] 4 2 POCI 3 / Preparation, IR Spectra and Crystal Structure of [WNCl 3 • P0Cl 3 ] 4 • 2 P0Cl 3".Zeitschrift für Naturforschung B.34(7): 942–948.doi:10.1515/znb-1979-0713.ISSN1865-7117.S2CID94076732.
  35. ^Liese, Werner; Dehnicke, Kurt; Walker, Ingeborg; Strähle, Joachim (1979-05-01)."Darstellung, Eigenschaften und Kristallstruktur von Rhenium(VII)-Nitridchlorid, ReNCl 4 / Preparation, Properties and Crystal Structure of Rhenium(VII) Nitride Chloride, ReNCl 4".Zeitschrift für Naturforschung B.34(5): 693–696.doi:10.1515/znb-1979-0509.ISSN1865-7117.S2CID96155024.
  36. ^abBinder, Anja; Maichle-Mössmer, Cäcilia; Niquet, Elke; Strähle, Joachim (July 2008)."Synthese und Kristallstruktur der Rhenium(VII)-Nitridchloride ReNCl4 und ReNCl4·H2O".Zeitschrift für anorganische und allgemeine Chemie(in German).634(8): 1326–1328.doi:10.1002/zaac.200800057.
  37. ^Abram, Ulrich; Braun, Martin; Abram, Sonja; Kirmse, Reinhard; Voigt, Andreas (1998)."[NBu4][ReNCl4]: Facile synthesis, structure, electron paramagnetic resonance spectroscopy and reactions".Journal of the Chemical Society, Dalton Transactions(2): 231–238.doi:10.1039/a705881k.
  38. ^"Kleinite Mineral Data".www.webmineral.com.Retrieved2023-08-31.
  39. ^"Mosesite Mineral Data".www.webmineral.com.Retrieved2023-08-31.
  40. ^Wang, Naizhou; Ye, Guojun; Hu, Guobing; Meng, Fanbao; Shang, Chao; Shi, Mengzhu; Ying, Jianjun; Chen, Xianhui (2019-08-05)."Absence of van der Waals Gap in Ternary Thorium Nitride ThNF and ThNCl".Inorganic Chemistry.58(15): 9897–9903.doi:10.1021/acs.inorgchem.9b01050.ISSN0020-1669.PMID31291102.S2CID195879442.
  41. ^Nakamura, Akio; Akabori, Mitsuo; Ogawa, Toru; Huntelaar, M. (April 2005)."Uranium nitride chloride UNCl: 30K-class ferromagnet with layered structure".Physica B: Condensed Matter.359–361: 1021–1023.Bibcode:2005PhyB..359.1021N.doi:10.1016/j.physb.2005.01.384.
Retrieved from "https://en.wikipedia.org/w/index.php?title=Nitride_chloride&oldid=1187946682"