Stable nuclide
This articleneeds additional citations forverification.(December 2018) |
Stable nuclidesareisotopesof achemical elementwhosenucleonsare in a configuration that does not permit them the surplus energy required to produce a radioactive emission. Thenucleiof such isotopes are not radioactive and unlikeradionuclidesdo not spontaneously undergoradioactive decay.[1]When these nuclides are referred to in relation to specific elements they are usually called that element'sstable isotopes.
The 80 elements with one or more stable isotopes comprise a total of 251 nuclides that have not been shown to decay using current equipment. Of these 80 elements, 26 have only one stable isotope and are calledmonoisotopic.The other 56 have more than one stable isotope.Tinhas ten stable isotopes, the largest number of any element.
Definition of stability, and naturally occurring nuclides
[edit]Most naturally occurringnuclidesare stable (about 251; see list at the end of this article), and about 35 more (total of 286) are known to be radioactive with long enough half-lives (also known) to occur primordially. If the half-life of anuclideis comparable to, or greater than, the Earth's age (4.5 billion years), a significant amount will have survived since theformation of the Solar System,and then is said to beprimordial.It will then contribute in that way to the natural isotopic composition of a chemical element. Primordial radioisotopes are easily detected with half-lives as short as 700 million years (e.g.,235U). This is the present limit of detection,[citation needed]as shorter-lived nuclides have not yet been detected undisputedly in nature except when recently produced, such as decay products or cosmic ray spallation.
Many naturally occurring radioisotopes (another 53 or so, for a total of about 339) exhibit still shorter half-lives than 700 million years, but they are made freshly, as daughter products of decay processes of primordial nuclides (for example, radium from uranium), or from ongoing energetic reactions, such ascosmogenic nuclidesproduced by present bombardment of Earth bycosmic rays(for example,14C made from nitrogen).
Some isotopes that are classed as stable (i.e. no radioactivity has been observed for them) are predicted to have extremely long half-lives (sometimes 1018years or more).[2]If the predicted half-life falls into an experimentally accessible range, such isotopes have a chance to move from the list of stable nuclides to the radioactive category, once their activity is observed. For example,209Bi and180W were formerly classed as stable, but were found to bealpha-active in 2003. However, such nuclides do not change their status as primordial when they are found to be radioactive.
Most stable isotopes on Earth are believed to have been formed in processes ofnucleosynthesis,either in theBig Bang,or in generations of stars that preceded theformation of the Solar System.However, some stable isotopes also show abundance variations in the earth as a result of decay from long-lived radioactive nuclides. These decay-products are termedradiogenicisotopes, in order to distinguish them from the much larger group of 'non-radiogenic' isotopes.
Isotopes per element
[edit]Of the known chemical elements, 80 elements have at least one stable nuclide. These comprise the first 82 elements fromhydrogentolead,with the two exceptions,technetium(element 43) andpromethium(element 61), that do not have any stable nuclides. As of 2023, there were a total of 251 known "stable" nuclides. In this definition, "stable" means a nuclide that has never been observed to decay against the natural background. Thus, these elements have half-lives too long to be measured by any means, direct or indirect.
Stable isotopes:
- 1 element (tin) has 10 stable isotopes
- 5 elements have 7 stable isotopes apiece
- 7 elements have 6 stable isotopes apiece
- 11 elements have 5 stable isotopes apiece
- 9 elements have 4 stable isotopes apiece
- 5 elements have 3 stable isotopes apiece
- 16 elements have 2 stable isotopes apiece
- 26 elements have 1 single stable isotope.
These last 26 are thus calledmonoisotopic elements.[3]The mean number of stable isotopes for elements which have at least one stable isotope is 251/80 = 3.1375.
Physical magic numbers and odd and even proton and neutron count
[edit]Stability of isotopes is affected by the ratio of protons to neutrons, and also by presence of certainmagic numbersof neutrons or protons which represent closed and filled quantum shells. These quantum shells correspond to a set of energy levels within theshell modelof the nucleus; filled shells, such as the filled shell of 50 protons for tin, confers unusual stability on the nuclide. As in the case of tin, a magic number forZ,the atomic number, tends to increase the number of stable isotopes for the element.
Just as in the case of electrons, which have the lowest energy state when they occur in pairs in a given orbital, nucleons (both protons and neutrons) exhibit a lower energy state when their number is even, rather than odd. This stability tends to prevent beta decay (in two steps) of many even–even nuclides into another even–even nuclide of the same mass number but lower energy (and of course with two more protons and two fewer neutrons), because decay proceeding one step at a time would have to pass through an odd–odd nuclide of higher energy. Such nuclei thus instead undergodouble beta decay(or are theorized to do so) with half-lives several orders of magnitude larger than theage of the universe.This makes for a larger number of stable even–even nuclides, which account for 150 of the 251 total. Stable even–even nuclides number as many as threeisobarsfor some mass numbers, and up to seven isotopes for some atomic numbers.
Conversely, of the 251 known stable nuclides, only five have both an odd number of protonsandodd number of neutrons: hydrogen-2 (deuterium),lithium-6,boron-10,nitrogen-14,andtantalum-180m.Also, only four naturally occurring, radioactive odd–odd nuclides have a half-life >109years:potassium-40,vanadium-50,lanthanum-138,andlutetium-176.Odd–oddprimordial nuclidesare rare because most odd–odd nucleibeta-decay,because the decay products are even–even, and are therefore more strongly bound, due tonuclear pairing effects.[4]
Yet another effect of the instability of an odd number of either type of nucleon is that odd-numbered elements tend to have fewer stable isotopes. Of the 26monoisotopic elements(those with only one stable isotope), all but one have an odd atomic number, and all but one has an even number of neutrons: the single exception to both rules isberyllium.
The end of the stable elements occurs afterlead,largely because nuclei with 128 neutrons—two neutrons above themagic number126—are extraordinarily unstable and almost immediately alpha-decay.[5]This contributes to the very short half-lives ofastatine,radon,andfrancium.A similar phenomenon occurs to a much lesser extent with 84 neutrons—two neutrons above the magic number 82—where various isotopes oflanthanideelements alpha-decay.
Nuclear isomers, including a "stable" one
[edit]The 251 known stable nuclides include tantalum-180m, since even though its decay is automatically implied by its being "metastable", this has not been observed. All "stable" isotopes (stable by observation, not theory) are the ground states of nuclei, except for tantalum-180m, which is anuclear isomeror excited state. The ground state, tantalum-180, is radioactive with half-life 8 hours; in contrast, the decay of the nuclear isomer is extremely strongly forbidden by spin-parity selection rules. It has been reported by direct observation that the half-life of180mTa to gamma decay must be >1015years. Other possible modes of180mTa decay (beta decay, electron capture, and alpha decay) have also never been observed.
Still-unobserved decay
[edit]It is expected that improvement of experimental sensitivity will allow discovery of very mild radioactivity of some isotopes now considered stable. For example, in 2003 it was reported thatbismuth-209(the only primordial isotope of bismuth) is very mildly radioactive, with half-life (1.9 ± 0.2) × 1019 yr,[6][7]confirming earlier theoretical predictions[8]fromnuclear physicsthat bismuth-209 would very slowlyalpha decay.
Isotopes that are theoretically believed to be unstable but have not been observed to decay are termedobservationally stable.Currently there are 105 "stable" isotopes which are theoretically unstable, 40 of which have been observed in detail with no sign of decay, the lightest in any case being36Ar. Many "stable" nuclides are "metastable"in that they would release energy if they were to decay,[9]and are expected to undergo very rare kinds ofradioactive decay,includingdouble beta decay.
146 nuclides from 62 elements withatomic numbersfrom 1 (hydrogen) through 66 (dysprosium) except 43 (technetium), 61 (promethium), 62 (samarium), and 63 (europium) are theoretically stable to any kind of nuclear decay — except for the theoretical possibility ofproton decay,which has never been observed despite extensive searches for it; andspontaneous fission(SF), which is theoretically possible for the nuclides withatomic mass numbers≥ 93.[10]
Besides SF, other theoretical decay routes for heavier elements include:[10]
- alpha decay– 70 heavynuclides(the lightest two arecerium-142 andneodymium-143)
- double beta decay– 55 nuclides
- beta decay–tantalum-180m
- electron capture–tellurium-123, tantalum-180m
- double electron capture
- isomeric transition– tantalum-180m
These include all nuclides of mass 165 and greater.Argon-36is the lightest known "stable" nuclide which is theoretically unstable.[10]
The positivity of energy release in these processes means they are allowed kinematically (they do not violate conservation of energy) and, thus, in principle, can occur.[10]They are not observed due to strong but not absolute suppression, by spin-parity selection rules (for beta decays and isomeric transitions) or by the thickness of the potential barrier (for alpha and cluster decays and spontaneous fission).
Summary table for numbers of each class of nuclides
[edit]This is a summary table fromList of nuclides.Note that numbers are not exact and may change slightly in the future, as nuclides are observed to be radioactive, or new half-lives are determined to some precision.
Type of nuclide by stability class | Number of nuclides in class | Running total of nuclides in all classes to this point | Notes |
---|---|---|---|
Theoretically stable according to known decay modes, includingalpha decay,beta decay,isomeric transition,anddouble beta decay | 146 | 146 | Contains the first 66 elements, except 43, 61, 62, and 63. Ifspontaneous fissionis possible for the nuclides withmass numbers≥ 93, then all such nuclides are unstable, so that only the first 40 elements would be stable; also, ifprotons decay,then there are no stable nuclides. |
Energetically unstable to one or more known decay modes, but no decay yet seen. Considered stable until radioactivity confirmed. | 105[2][11] | 251 | Total is the observationally stable nuclides. All elements up tolead(excepttechnetiumandpromethium) are included. |
Radioactiveprimordial nuclides. | 35 | 286 | Includesbismuth,thorium,anduranium |
Radioactive nonprimordial, but naturally occurring on Earth. | ~61 significant | ~347 significant | Cosmogenic nuclidesfrom cosmic rays; daughters of radioactive primordials such asfrancium,etc. |
List of stable nuclides
[edit]The primordial radionuclides have been included for comparison; they are italicized and offset from the list of stable nuclides proper.
- Hydrogen-1
- Hydrogen-2
- Helium-3
- Helium-4
- no mass number 5
- Lithium-6
- Lithium-7
- no mass number 8
- Beryllium-9
- Boron-10
- Boron-11
- Carbon-12
- Carbon-13
- Nitrogen-14
- Nitrogen-15
- Oxygen-16
- Oxygen-17
- Oxygen-18
- Fluorine-19
- Neon-20
- Neon-21
- Neon-22
- Sodium-23
- Magnesium-24
- Magnesium-25
- Magnesium-26
- Aluminium-27
- Silicon-28
- Silicon-29
- Silicon-30
- Phosphorus-31
- Sulfur-32
- Sulfur-33
- Sulfur-34
- Sulfur-36
- Chlorine-35
- Chlorine-37
- Argon-36(2E)
- Argon-38
- Argon-40
- Potassium-39
- Potassium-40(B, E) – long-lived primordial radionuclide
- Potassium-41
- Calcium-40(2E)*
- Calcium-42
- Calcium-43
- Calcium-44
- Calcium-46(2B)*
- Calcium-48(2B) – long-lived primordial radionuclide (B also predicted possible)
- Scandium-45
- Titanium-46
- Titanium-47
- Titanium-48
- Titanium-49
- Titanium-50
- Vanadium-50(B, E) – long-lived primordial radionuclide
- Vanadium-51
- Chromium-50(2E)*
- Chromium-52
- Chromium-53
- Chromium-54
- Manganese-55
- Iron-54(2E)*
- Iron-56
- Iron-57
- Iron-58
- Cobalt-59
- Nickel-58(2E)*
- Nickel-60
- Nickel-61
- Nickel-62
- Nickel-64
- Copper-63
- Copper-65
- Zinc-64(2E)*
- Zinc-66
- Zinc-67
- Zinc-68
- Zinc-70(2B)*
- Gallium-69
- Gallium-71
- Germanium-70
- Germanium-72
- Germanium-73
- Germanium-74
- Germanium-76(2B) – long-lived primordial radionuclide
- Arsenic-75
- Selenium-74(2E)
- Selenium-76
- Selenium-77
- Selenium-78
- Selenium-80(2B)
- Selenium-82(2B) – long-lived primordial radionuclide
- Bromine-79
- Bromine-81
- Krypton-78(2E) – long-lived primordial radionuclide
- Krypton-80
- Krypton-82
- Krypton-83
- Krypton-84
- Krypton-86(2B)
- Rubidium-85
- Rubidium-87(B) – long-lived primordial radionuclide
- Strontium-84(2E)*
- Strontium-86
- Strontium-87
- Strontium-88
- Yttrium-89
- Zirconium-90
- Zirconium-91
- Zirconium-92
- Zirconium-94(2B)*
- Zirconium-96(2B) – long-lived primordial radionuclide (B also predicted possible)
- Niobium-93
- Molybdenum-92(2E)*
- Molybdenum-94
- Molybdenum-95
- Molybdenum-96
- Molybdenum-97
- Molybdenum-98(2B)*
- Molybdenum-100(2B) – long-lived primordial radionuclide
- Technetium–no stable isotopes
- Ruthenium-96(2E)*
- Ruthenium-98
- Ruthenium-99
- Ruthenium-100
- Ruthenium-101
- Ruthenium-102
- Ruthenium-104(2B)
- Rhodium-103
- Palladium-102(2E)
- Palladium-104
- Palladium-105
- Palladium-106
- Palladium-108
- Palladium-110(2B)*
- Silver-107
- Silver-109
- Cadmium-106(2E)*
- Cadmium-108(2E)*
- Cadmium-110
- Cadmium-111
- Cadmium-112
- Cadmium-113(B) – long-lived primordial radionuclide
- Cadmium-114(2B)*
- Cadmium-116(2B) – long-lived primordial radionuclide
- Indium-113
- Indium-115(B) – long-lived primordial radionuclide
- Tin-112(2E)*
- Tin-114
- Tin-115
- Tin-116
- Tin-117
- Tin-118
- Tin-119
- Tin-120
- Tin-122(2B)*
- Tin-124(2B)*
- Antimony-121
- Antimony-123
- Tellurium-120(2E)*
- Tellurium-122
- Tellurium-123(E)*
- Tellurium-124
- Tellurium-125
- Tellurium-126
- Tellurium-128(2B) – long-lived primordial radionuclide
- Tellurium-130(2B) – long-lived primordial radionuclide
- Iodine-127
- Xenon-124(2E) – long-lived primordial radionuclide
- Xenon-126(2E)
- Xenon-128
- Xenon-129
- Xenon-130
- Xenon-131
- Xenon-132
- Xenon-134(2B)*
- Xenon-136(2B) – long-lived primordial radionuclide
- Caesium-133
- Barium-130(2E) – long-lived primordial radionuclide
- Barium-132(2E)*
- Barium-134
- Barium-135
- Barium-136
- Barium-137
- Barium-138
- Lanthanum-138(B, E) – long-lived primordial radionuclide
- Lanthanum-139
- Cerium-136(2E)*
- Cerium-138(2E)*
- Cerium-140
- Cerium-142(α, 2B)*
- Praseodymium-141
- Neodymium-142
- Neodymium-143(α)
- Neodymium-144(α) – long-lived primordial radionuclide
- Neodymium-145(α)*
- Neodymium-146(α, 2B)*
- no mass number 147§
- Neodymium-148(α, 2B)*
- Neodymium-150(2B) – long-lived primordial radionuclide
- Promethium-no stable isotopes
- Samarium-144(2E)
- Samarium-146(α) – probable long-lived primordial radionuclide
- Samarium-147(α) – long-lived primordial radionuclide
- Samarium-148(α) – long-lived primordial radionuclide
- Samarium-149(α)*
- Samarium-150(α)
- no mass number 151§
- Samarium-152(α)
- Samarium-154(2B)*
- Europium-151(α) – long-lived primordial radionuclide
- Europium-153(α)*
- Gadolinium-152(α) – long-lived primordial radionuclide (2E also predicted possible)
- Gadolinium-154(α)
- Gadolinium-155(α)
- Gadolinium-156
- Gadolinium-157
- Gadolinium-158
- Gadolinium-160(2B)*
- Terbium-159
- Dysprosium-156(α, 2E)*
- Dysprosium-158(α)
- Dysprosium-160(α)
- Dysprosium-161(α)
- Dysprosium-162(α)
- Dysprosium-163
- Dysprosium-164
- Holmium-165(α)
- Erbium-162(α, 2E)*
- Erbium-164(α, 2E)
- Erbium-166(α)
- Erbium-167(α)
- Erbium-168(α)
- Erbium-170(α, 2B)*
- Thulium-169(α)
- Ytterbium-168(α, 2E)*
- Ytterbium-170(α)
- Ytterbium-171(α)
- Ytterbium-172(α)
- Ytterbium-173(α)
- Ytterbium-174(α)
- Ytterbium-176(α, 2B)*
- Lutetium-175(α)
- Lutetium-176(B) – long-lived primordial radionuclide (α, E also predicted possible)
- Hafnium-174(α) – long-lived primordial radionuclide (2E also predicted possible)
- Hafnium-176(α)
- Hafnium-177(α)
- Hafnium-178(α)
- Hafnium-179(α)
- Hafnium-180(α)
- Tantalum-180m(α, B, E, IT)*^
- Tantalum-181(α)
- Tungsten-180(α) – long-lived primordial radionuclide (2E also predicted possible)
- Tungsten-182(α)*
- Tungsten-183(α)*
- Tungsten-184(α)*
- Tungsten-186(α, 2B)*
- Rhenium-185(α)
- Rhenium-187(B) – long-lived primordial radionuclide (A also predicted possible)
- Osmium-184(α) – long-lived primordial radionuclide (2E also predicted possible)
- Osmium-186(α) – long-lived primordial radionuclide
- Osmium-187(α)
- Osmium-188(α)
- Osmium-189(α)
- Osmium-190(α)
- Osmium-192(α, 2B)*
- Iridium-191(α)
- Iridium-193(α)
- Platinum-190(α) – long-lived primordial radionuclide (2E also predicted possible)
- Platinum-192(α)*
- Platinum-194(α)
- Platinum-195(α)*
- Platinum-196(α)
- Platinum-198(α, 2B)*
- Gold-197(α)
- Mercury-196(α, 2E)*
- Mercury-198(α)
- Mercury-199(α)
- Mercury-200(α)
- Mercury-201(α)
- Mercury-202(α)
- Mercury-204(2B)
- Thallium-203(α)
- Thallium-205(α)
- Lead-204(α)*
- Lead-206(α)*
- Lead-207(α)*
- Lead-208(α)*
- Bismuth^^and above –
- no stable isotopes
- no mass number 209 and above
- Bismuth-209(α) – long-lived primordial radionuclide
- Thorium-232(α, SF) – long-lived primordial radionuclide (2B also predicted possible)
- Uranium-235(α, SF) – long-lived primordial radionuclide
- Uranium-238(α, 2B, SF) – long-lived primordial radionuclide
- Plutonium-244(α, SF) – probable long-lived primordial radionuclide (2B also predicted possible)
- Bismuth^^and above –
Abbreviations for predicted unobserved decay:[12][2][11]
αfor alpha decay,Bfor beta decay,2Bfor double beta decay,Efor electron capture,2Efor double electron capture,ITfor isomeric transition,SFfor spontaneous fission,*for the nuclides whose half-lives have lower bound. Double beta decay has only been listed when beta decay is not also possible.
^Tantalum-180m is a "metastable isotope", meaning it is an excitednuclear isomerof tantalum-180. Seeisotopes of tantalum.However, the half-life of this nuclear isomer is so long that it has never been observed to decay, and it thus is an "observationally stable"primordial nuclide,a rare isotope of tantalum. This is the only nuclear isomer with a half-life so long that it has never been observed to decay. It is thus included in this list.
^^Bismuth-209was long believed to be stable, due to its half-life of 2.01×1019years, which is more than a billion times the age of the universe.
§Europium-151andsamarium-147areprimordial nuclideswith very long half-lives of 4.62×1018years and 1.066×1011years, respectively.
See also
[edit]- Isotope geochemistry
- List of elements by stability of isotopes
- List of nuclides(991 nuclides in order of stability, all with half-lives over one hour)
- Mononuclidic element
- Periodic table
- Primordial nuclide
- Radionuclide
- Stable isotope ratio
- Table of nuclides
- Valley of stability
References
[edit]- ^"DOE explains... Isotopes".Department of Energy, United States. Archived fromthe originalon 14 April 2022.Retrieved11 January2023.
- ^abcBelli, P.; Bernabei, R.; Danevich, F. A.; et al. (2019). "Experimental searches for rare alpha and beta decays".European Physical Journal A.55(8): 140–1–140–7.arXiv:1908.11458.Bibcode:2019EPJA...55..140B.doi:10.1140/epja/i2019-12823-2.ISSN1434-601X.S2CID201664098.
- ^Sonzogni, Alejandro."Interactive Chart of Nuclides".National Nuclear Data Center: Brook haven National Laboratory. Archived fromthe originalon 2018-10-10.Retrieved2008-06-06.
- ^Various (2002). Lide, David R. (ed.).Handbook of Chemistry & Physics(88th ed.). CRC.ISBN978-0-8493-0486-6.OCLC179976746.Archived fromthe originalon 2017-07-24.Retrieved2008-05-23.
- ^Kelkar, N. G.; Nowakowski, M. (2016). "Signature of theN= 126 shell closure in dwell times of alpha-particle tunneling ".Journal of Physics G: Nuclear and Particle Physics.43(105102).arXiv:1610.02069.doi:10.1088/0954-3899/43/10/105102.
- ^"WWW Table of Radioactive Isotopes".[permanent dead link]
- ^Marcillac, Pierre de; Noël Coron; Gérard Dambier; Jacques Leblanc & Jean-Pierre Moalic (2003). "Experimental detection of α-particles from the radioactive decay of natural bismuth".Nature.422(6934): 876–878.Bibcode:2003Natur.422..876D.doi:10.1038/nature01541.PMID12712201.S2CID4415582.
- ^de Carvalho H. G., de Araújo Penna M. (1972)."Alpha-activity of209Bi ".Lett. Nuovo Cimento.3(18): 720–722.doi:10.1007/BF02824346.
- ^"NNDC – Atomic Masses".www.nndc.bnl.gov.Archived fromthe originalon 2019-01-11.Retrieved2009-01-17.
- ^abcdNucleonica website
- ^abTretyak, V.I.; Zdesenko, Yu.G. (2002). "Tables of Double Beta Decay Data — An Update".At. Data Nucl. Data Tables.80(1): 83–116.Bibcode:2002ADNDT..80...83T.doi:10.1006/adnd.2001.0873.
- ^"Nucleonica:: Web driven nuclear science".
Book references
[edit]- Various (2002). Lide, David R. (ed.).Handbook of Chemistry & Physics(88th ed.). CRC.ISBN978-0-8493-0486-6.OCLC179976746.Archived fromthe originalon 2017-07-24.Retrieved2008-05-23.
External links
[edit]- The LIVEChart of Nuclides – IAEA
- AlphaDelta: Stable Isotope fractionation calculator
- National Isotope Development CenterReference information on isotopes, and coordination and management of isotope production, availability, and distribution
- Isotope Development & Production for Research and Applications (IDPRA)U.S. Department of Energy program for isotope production and production research and development
- IsosciencesArchived2021-01-18 at theWayback MachineUse and development of stable isotope labels in synthetic and biological molecules