Rhenium disulfide

Rhenium disulfide

Names
IUPAC name Bis(sulfanylidene)rhenium
Other names Rhenium(IV) sulfide
Identifiers
CAS Number	12038-63-0
3D model (JSmol)	Interactive image
ChemSpider	74775
ECHA InfoCard	100.031.695
EC Number	234-878-3
PubChemCID	82864
CompTox Dashboard(EPA)	DTXSID7065201
InChI InChI=1S/Re.2S Key: USWJSZNKYVUTIE-UHFFFAOYSA-N
SMILES S=[Re]=S
Properties
Chemical formula	ReS2
Molar mass	250.337 g/mol
Odor	odorless
Density	7.6 g/cm3
Solubility in water	insoluble
Structure
Crystal structure	Triclinic,aP12,space groupP1,No 2
Lattice constant	a= 0.6352 nm,b= 0.6446 nm,c= 1.2779 nm α = 91.51°, β = 105.17°, γ = 118.97°
Formula units(Z)	8
Related compounds
Otheranions	Rhenium(IV) oxide Rhenium diselenide Rhenium ditelluride
Othercations	Manganese diselenide
Except where otherwise noted, data are given for materials in theirstandard state(at 25 °C [77 °F], 100 kPa). Infobox references

Rhenium disulfideis aninorganic compoundofrheniumandsulfurwith the formula ReS₂.It has a layered structure where atoms are strongly bonded within each layer. The layers are held together by weakVan der Waals bonds,and can be easily peeled off from the bulk material.

Production

ReS₂is found in nature as the mineralrheniite.It can be synthesized from the reaction between rhenium and sulfur at 1000 °C, or the decomposition ofrhenium(VII) sulfideat 1100 °C:

Re + 2 S → ReS₂

Re₂S₇→ 2 ReS₂+ 3 S

Nanostructured ReS₂can usually be achieved through mechanical exfoliation,chemical vapor deposition(CVD), and chemical and liquid exfoliations. Larger crystals can be grown with the assistance of liquid carbonate flux at high pressure. It is widely used in electronic and optoelectronic device, energy storage, photocatalytic and electrocatalytic reactions.

Properties

It is a two-dimensional (2D) group VIItransition metal dichalcogenide(TMD). ReS₂was isolated down to monolayers which is only one unit cell in thickness for the first time in 2014.These monolayers have shown layer-independent electrical, optical, and vibrational properties much different from other TMDs.

Structure

Bulk ReS₂has a layered structure and a platelet-like habit. Different crystal structures were proposed for ReS₂based on single-crystal X-ray diffraction studies. While all authors agree that the lattice is triclinic, the reported cell parameters and atomic arrangements slightly differ. The earliest workdescribes ReS₂in a triclinic unit cell (sp. gr. P${\bar {1}}$,a = 0.6455 nm, b = 0.6362 nm, c = 0.6401 nm, α = 105.04°, β = 91.60°, γ = 118.97°) as a distorted variant of the CdCl₂prototype (1T structure, trigonal space group R${\bar {3}}$m). In comparison with ideal octahedral coordination of the metal atoms in CdCl₂,the Re atoms in ReS₂are displaced from the centers of the surrounding Se₆octahedra and form Re₄clusters that are linked to chains in the b direction. A later studyproposed a more accurate description of the crystal structure. It reports a different triclinic cell (sp. gr. P${\bar {1}}$,a = 0.6352 nm, b = 0.6446 nm, c = 1.2779 nm, α = 91.51°, β = 105.17°, γ = 118.97°) with the doubled c parameter and swapped a and b, α and β. There are two layers in this unit cell, related by symmetry centers, and the chains of clusters run along the a axis. Each layer form parallelogram-shaped connected clusters with Re-Re distances of ca. 0.27-0.28 nm in the cluster, and ca. 0.29 nm between clusters. There is one more structure description of ReS₂published inin yet another triclinic cell (sp. gr. P${\bar {1}}$,a = 0.6417 nm, b = 0.6510 nm, c = 0.6461 nm, α = 121.10°, β = 88.38°, γ = 106.47°) where only one layer is present and the centers of symmetry are in the Re layer. The current consent is that the latter work might have overlooked the doubling of the c parameter captured in.