Jump to content

Triphosphoric acid

From Wikipedia, the free encyclopedia
Triphosphoric acid
Structure of triphosphoric acid
Names
IUPAC name
Diphosphono hydrogenphosphate
Systematic IUPAC name
Triphosphoric acid
Tripolyphosphoric acid
Other names
Diphosphonophosphoric acid
Phosphono trihydrogenpyrophosphate
Phosphonopyrophosphoric acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.030.752Edit this at Wikidata
EC Number
  • 233-840-3
KEGG
UNII
  • InChI=1S/H5O10P3/c1-11(2,3)9-13(7,8)10-12(4,5)6/h(H,7,8)(H2,1,2,3)(H2,4,5,6)☒N
    Key: UNXRWKVEANCORM-UHFFFAOYSA-N☒N
  • OP(=O)(O)OP(=O)(O)OP(=O)(O)O
Properties
H5P3O10
Molar mass 257.95 g/mol
Acidity(pKa) See body
Conjugate base Triphosphate
Hazards
Occupational safety and health(OHS/OSH):
Main hazards
Corrosive (C)
Except where otherwise noted, data are given for materials in theirstandard state(at 25 °C [77 °F], 100 kPa).

Triphosphoric acid(alsotripolyphosphoric acid), with formula H5P3O10,is acondensedform ofphosphoric acid.In the family ofphosphoric acids,it is the nextpolyphosphoric acidafterpyrophosphoric acid,H4P2O7,also called diphosphoric acid.

Compounds such as ATP (adenosine triphosphate) areestersof triphosphoric acid.

Triphosphoric acid has not been obtained in crystalline form. The equilibrium mixture with an overall composition corresponding to H5P3O10contains about 20% of triphosphoric acid. A solution of the pure species can be obtained by ion exchange of the sodium salt,sodium triphosphate,at 0 °C.[1]

Triphosporic acid is apentaprotic acid,meaning that it can release five protons in basic enough conditions. Sources differ on the corresponding pKavalues:

References

[edit]
  1. ^abCorbridge, D. (1995). "Chapter 3: Phosphates".Studies in inorganic Chemistry vol. 20.Elsevier Science B.V. pp. 169–305.ISBN0-444-89307-5.
  2. ^Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.),Inorganic Chemistry,translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, p. 729,ISBN0-12-352651-5