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Zirconium disulfide

From Wikipedia, the free encyclopedia
Zirconium(IV) sulfide[1]
Names
IUPAC name
Zirconium(IV) sulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.701 Edit this at Wikidata
EC Number
  • 234-885-1
  • InChI=1S/2S.Zr/q2*-2;+4
    Key: XWPGCGMKBKONAU-UHFFFAOYSA-N
  • [S-2].[S-2].[Zr+4]
Properties
ZrS2
Molar mass 155.356 g/mol
Appearance red-brown crystals
Density 3.82 g/cm3
Melting point 1,480 °C (2,700 °F; 1,750 K)
insoluble
Structure
Rhombohedral, hP3
P-3m1, No. 164
octahedral
Hazards
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Zirconium(IV) sulfide is the inorganic compound with the formula ZrS2. It is a violet-brown solid. It adopts a layered structure similar to that of cadmium iodide.

Like the closely related titanium disulfide, ZrS2 is prepared by heating sulfur and zirconium metal. It can be purified by vapor transport using iodine.[2]

References

[edit]
  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–96, ISBN 0-8493-0594-2
  2. ^ Lawrence E. Conroy "Group IV Sulfides" Inorganic Synthesis 1970, XII, 158. doi:10.1002/9780470132432.ch28