Borate sulfide
Borate sulfidesare chemicalmixed anion compoundsthat contain any kind ofborateandsulfideions. They are distinct fromthioboratesin which sulfur atoms replace oxygen in borates. There are also analogousborate selenides,with selenium ions instead of sulfur.
List
[edit]| name | chem | mw | crystal system | space group | unit cell | volume | density | comments | references |
|---|---|---|---|---|---|---|---|---|---|
| Zn4B6O12S | I43m | NLO 1.9 × KDP | [1] | ||||||
| cadmium sulfur boracite | Cd3B7O13S2 | cubic | F43c | [2] | |||||
| La6Nb2MgSB8O26 | trigonal | P3 | a=8.2137c=8.8601 | clear | [3] | ||||
| Ce6Nb2MgSB8O26 | trigonal | P3 | a=8.1672c=8.8093 | clear | [3] | ||||
| Pr6Nb2MgSB8O26 | trigonal | P3 | a=8.1362c=8.7716 | yellowish green | [3] | ||||
| Nd6Nb2MgSB8O26 | trigonal | P3 | a=8.1135c=8.7469 | clear | [3] | ||||
| EBOS | Eu2B5O9S | 534.03 | orthorhombic | Pnn2 | a=11.2909 b=11.3742 c=6.4440 Z=4 | 827.57 | 4.286 | black | [4] |
| EBOSI | Eu4.5(B5O9)2SI | 1238.88 | orthorhombic | Pnn2 | a=11.529 b=11.550 c=6.5070 Z=2 | 866.5 | 4.748 | yellow-green band gap 1.98 eV | [4] |
| EMSBO | Eu9MgS2B20O41 | 2328.27 | Hexagonal | P63/m | a=8.2708 c=24.919 Z=2 | 1476.3 | 5.238 | brown | [5] |
| Eu6Ta2MgSB8O26 | 1832.51 | trigonal | P3 | a=8.0431 c=8.6486 Z=1 | 484.53 | 6.280 | [6] | ||
| Sm3S3BO3 | 606.04 | triclinic | P1 | a=4.0173 b=7.647 c=11.241 α=91.339β=91.275γ=90.349 Z=2 | 345.14 | 5.832 | green; band gap 2.5 eV | [7] | |
| Gd3S3BO3 | 626.74 | triclinic | P1 | a=3.9725 b=7.5945 c=11.182 α=91.402β=91.093γ=90.206 Z=2 | 337.30 | 6.173 | pale yellow; band gap 2.65 eV | [8] |
References
[edit]- ^Zhou, Wenfeng; Yao, Wen-Dong; Tang, Ru-Ling; Xue, Huaiguo; Guo, Sheng-Ping (2021-06-25)."Second-order nonlinear optical and photoelectric properties of Zn4B6O12S".Journal of Alloys and Compounds.867:158879.doi:10.1016/j.jallcom.2021.158879.ISSN0925-8388.S2CID233544941.
- ^Gould, R O; Nelmes, R J; Gould, S E B (1981-12-10)."Structural studies of boracites. VII. Cadmium sulphur boracite at room temperature".Journal of Physics C: Solid State Physics.14(34): 5259–5267.Bibcode:1981JPhC...14.5259G.doi:10.1088/0022-3719/14/34/008.ISSN0022-3719.
- ^abcdTang, Ru-Ling; Wei, Yu-Long; Chi, Yang; Shi, Zhi-Hui; Liu, Wenlong; Guo, Sheng-Ping (2022-06-13)."Cation Regulation to Investigate the Chalcogenide Borate RE 6 Nb 2 MgSB 8 O 26 (RE = La–Nd) Family".Inorganic Chemistry.61(23): 8653–8661.doi:10.1021/acs.inorgchem.2c00033.ISSN0020-1669.PMID35622004.S2CID249095609.
- ^abChi, Yang; Xue, Huai-Guo; Guo, Sheng-Ping (2020-01-21)."Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material".Inorganic Chemistry.59(2): 1547–1555.doi:10.1021/acs.inorgchem.9b03426.ISSN0020-1669.PMID31909601.S2CID210043683.
- ^Chi, Yang; Xu, Jing; Xue, Huai-Guo; Zhang, Yueping; Chen, Xiaolong; Whangbo, Myung-Hwan; Guo, Sheng-Ping; Deng, Shuiquan (2019-06-19)."Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu9MgS2B20O41".Journal of the American Chemical Society.141(24): 9533–9536.doi:10.1021/jacs.9b04627.ISSN0002-7863.PMID31184141.S2CID184485492.
- ^Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16)."A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster".Inorganic Chemistry.59(6): 3532–3536.doi:10.1021/acs.inorgchem.0c00086.ISSN0020-1669.PMID32090554.S2CID211263182.
- ^Guo, Sheng-Ping; Chi, Yang; Xue, Huai-Guo (2015-12-07)."Sm 3 S 3 BO 3: The First Sulfide Borate without S–O and B–S Bonds".Inorganic Chemistry.54(23): 11052–11054.doi:10.1021/acs.inorgchem.5b01930.ISSN0020-1669.PMID26558599.
- ^Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01)."Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)".New Journal of Chemistry.40(8): 6720–6727.doi:10.1039/C6NJ00549G.ISSN1369-9261.