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Saltpetre works

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A typical nitrary (Germany, circa 1580) with leaching deposits (C) filled with decaying vegetal material mixed with manure. A worker collects effloresced saltpeter from deposits, transporting it then to be concentrated in the factory (A) boilers.

Asaltpetre worksornitrary[1]is a place of production ofpotassium nitrateorsaltpetreused primarily for the manufacture ofgunpowder.The saltpeter occurs naturally in certain places like the "Caves of Salnitre" (Collbató) known since the Neolithic. In the "Cova del Rat Penat",guano(bat excrements) deposited over thousands of years became saltpeter after beingleachedby the action of rainwater.

Manufacture[edit]

Saltpeter Mine Ruins in Mammoth Cave

The process involved burial of excrements (human or animal) in the fields prepared for that purpose beside the nitraries, watering them and waiting until the leaching process did its job; after a certain time, operators gathered the saltpeter that "came out" to the ground surface byefflorescence.Then they transported it to be concentrated byebullitionin the boiler plant.[2][3]

History[edit]

Besides "Montepellusanus",[4]during the thirteenth century (and beyond) the only supply ofsaltpeteracross Christian Europe (according to "De Alchimia" in 3 manuscripts of Michael Scot, 1180–1236) was "found in Spain in Aragonia in a certain mountain near the sea", (which can only be Catalonia):saraceni apellant ipsum borax et credunt quod sit alumen.Et in Hispania invenitur versus Argoniam in quodam monte juxta mare. et apellant ipsum hispani alumen acetum activum.[5][4][6]

In fact in 1561,Elizabeth I of Englandat war withPhilip II of Spain,became unable to import the saltpeter (of which theKingdom of Englandhad no home production), and had to pay "300 pounds gold" to the German captain Gerrard Honrik for the manual "Instructions for making salpeter to growe"[7](the secret of the "Feuerwerkbuch" -the nitraries-).[8]

In 1783,Giuseppe Maria GioveneandAlberto Fortistogether discovered a "natural nitrary" in a doline close toMolfetta,Italy, whose name isPulo di Molfetta.The two scientists discovered that saltpeter formed inside the walls of the caves of the doline, under certain conditions of humidity and temperature.[9]Prior to the discovery,nitrarieswere widespread all over theKingdom of Naples.Manure was collected by the government and used to makesaltpeter,which was a key ingredient for gunpowder. After the discovery, it was suggested that manure could be used for agriculture, in order to increase the production, rather than to make gunpowder.[10]

The discovery also generated issues; in particular, it was initially challenged by some scholars. Subsequently, chemistGiuseppe Vairoand his pupilAntonio Pitaroconfirmed the discovery. This undoubtedly damaged producers of artificial saltpetre, and some scholars, most likely supported by the producers, tried to dismiss the discovery. Following the above discovery, naturalists sent by academies from all Europe came in large number to visitPulo di Molfetta,since the saltpeter was a fundamental ingredient in the production ofgunpowderand these deposits were of considerable strategic interest.[11]

Soon, the government started to extract saltpetre fromPulo di Molfettaand today thedolinestill contains the remains of the ancient plant used to extract saltpetre, making it a site ofindustrial archaeology.Pulo di Molfettais currently not open to tourists.[12]

Short thereafter,Giuseppe Maria Giovenediscovered that saltpetre also formed in other caves ofApulia.[13][14]

See also[edit]

References[edit]

  1. ^John Spencer Bassett; Edwin Mims; William Henry Glasson; William Preston Few; William Kenneth Boyd; William Hane Wannamaker (1904).The South Atlantic Quarterly.Duke University Press.Retrieved22 February2013.
  2. ^Paul-Antoine Cap (1857).Etudes biographiques pour servir à l'histoire des sciences...: sér. Chimistes.V. Masson. pp. 294–.ISBN978-0-608-37253-2.Retrieved23 February2013.
  3. ^Oscar Gutman (1906).Monumenta pulveris pyrii. Repr.Artists Press Balham. pp. 50–.
  4. ^abJames Riddick Partington (1960).A history of Greek fire and.JHU Press. pp.89 –.ISBN978-0-8018-5954-0.
  5. ^James Riddick Partington (1960).A history of Greek fire and March 2012.JHU Press. pp.311 –.ISBN978-0-8018-5954-0.
  6. ^Alexander Adam (1805).A compendious dictionary of the Latin tongue: for the use of public Seminar and private March 2012.Printed for T. Cachorro and W. Davies, by C. Stewart, London, Bell and Bradfute, W. Creech.
  7. ^Cocroft, W.D. (2014).Dangerous Energy: The Archaeology of Gunpowder and Military Explosives Manufacture.English Heritage Series. Historic England Publishing. p. 5.ISBN978-1-84802-181-5.Retrieved2022-06-08.
  8. ^SP Dom Elizabeth vol.xvi 29-30 (1589)
  9. ^necrologio-giovene, pag. 39
  10. ^"Opuscoli scelti sulle scienze e sulle arti tratti dagli Atti delle Accademie, e dalle altre Collezioni filosofiche, e letterarie, e dalle opere più recenti inglesi, tedesche, francesi, latine, e italiane, e da manoscritti originali, e inediti: 12".1789.
  11. ^elogio-storico, pagg. 8-10
  12. ^"PER VEDERE IL PULO DI MOLFETTA ACCONTENTATEVI DI ARRAMPICARVI!".molfettafree.it.[permanent dead link]
  13. ^elogio-storico, pagg. 9-10
  14. ^lettera-a-fortis-1784

Bibliography[edit]