Water vapor
Water vapor,water vapouroraqueous vaporis thegaseousphase ofwater.It is onestateof water within thehydrosphere.Watervaporcan be produced from theevaporationorboilingof liquid water or from thesublimationofice.Water vapor is transparent, like most constituents of the atmosphere.[1]Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed bycondensation.It is less dense than most of the other constituents ofairand triggersconvectioncurrents that can lead to clouds and fog.
Being a component of Earth's hydrosphere and hydrologic cycle, it is particularly abundant inEarth's atmosphere,where it acts as agreenhouse gasand warming feedback, contributing more to total greenhouse effect than non-condensable gases such ascarbon dioxideandmethane.Use of water vapor, assteam,has been important for cooking, and as a major component in energy production and transport systems since theindustrial revolution.
Water vapor is a relatively common atmospheric constituent, present even in thesolar atmosphereas well as every planet in theSolar Systemand manyastronomical objectsincludingnatural satellites,cometsand even largeasteroids.Likewise the detection ofextrasolarwater vapor would indicate a similar distribution in other planetary systems. Water vapor can also be indirect evidence supporting the presence of extraterrestrial liquid water in the case of some planetary mass objects.
Water vapor, which reacts to temperature changes, is referred to as a 'feedback', because it amplifies the effect of forces that initially cause the warming. So, it is a greenhouse gas.[2]
Properties
[edit]Evaporation
[edit]Whenever a water molecule leaves a surface and diffuses into a surrounding gas, it is said to haveevaporated.Each individual water molecule which transitions between a more associated (liquid) and a less associated (vapor/gas) state does so through the absorption or release ofkinetic energy.The aggregate measurement of this kinetic energy transfer is defined as thermal energy and occurs only when there is differential in the temperature of the water molecules. Liquid water that becomes water vapor takes a parcel of heat with it, in a process calledevaporative cooling.[3]The amount of water vapor in the air determines how frequently molecules will return to the surface. When a net evaporation occurs, the body of water will undergo a net cooling directly related to the loss of water.
In the US, the National Weather Service measures the actual rate of evaporation from a standardized "pan" open water surface outdoors, at various locations nationwide. Others do likewise around the world. The US data is collected and compiled into an annual evaporation map.[4]The measurements range from under 30 to over 120 inches per year. Formulas can be used for calculating the rate of evaporation from a water surface such as a swimming pool.[5][6]In some countries, the evaporation rate far exceeds theprecipitationrate.
Evaporative cooling is restricted byatmospheric conditions.Humidityis the amount of water vapor in the air. The vapor content of air is measured with devices known ashygrometers.The measurements are usually expressed asspecific humidityor percentrelative humidity.The temperatures of the atmosphere and the water surface determine the equilibrium vapor pressure; 100% relative humidity occurs when the partial pressure of water vapor is equal to the equilibrium vapor pressure. This condition is often referred to as complete saturation. Humidity ranges from 0 grams per cubic metre in dry air to 30 grams per cubic metre (0.03 ounce per cubic foot) when the vapor is saturated at 30 °C.[7]
Sublimation
[edit]Sublimationis the process by which water molecules directly leave the surface of ice without first becoming liquid water. Sublimation accounts for the slow mid-winter disappearance of ice and snow at temperatures too low to cause melting.Antarcticashows this effect to a unique degree because it is by far the continent with the lowest rate of precipitation on Earth.[8]As a result, there are large areas wheremillenniallayers of snow have sublimed, leaving behind whatever non-volatile materials they had contained. This is extremely valuable to certain scientific disciplines, a dramatic example being the collection ofmeteoritesthat are left exposed in unparalleled numbers and excellent states of preservation.
Sublimation is important in the preparation of certain classes of biological specimens forscanning electron microscopy.Typically the specimens are prepared bycryofixationandfreeze-fracture,after which the broken surface is freeze-etched, being eroded by exposure to vacuum until it shows the required level of detail. This technique can display protein molecules,organellestructures andlipid bilayerswith very low degrees of distortion.
Condensation
[edit]Water vapor will only condense onto another surface when that surface is cooler than thedew pointtemperature, or when thewater vapor equilibriumin air has been exceeded. When water vapor condenses onto a surface, a net warming occurs on that surface.[9]The water molecule brings heat energy with it. In turn, the temperature of the atmosphere drops slightly.[10]In the atmosphere, condensation produces clouds, fog and precipitation (usually only when facilitated bycloud condensation nuclei). Thedew pointof an air parcel is the temperature to which it must cool before water vapor in the air begins to condense. Condensation in the atmosphere forms cloud droplets.
Also, a net condensation of water vapor occurs on surfaces when the temperature of the surface is at or below the dew point temperature of the atmosphere.Depositionis aphase transitionseparate from condensation which leads to the direct formation of ice from water vapor.Frostand snow are examples of deposition.
There are several mechanisms of cooling by which condensation occurs: 1) Direct loss of heat by conduction or radiation. 2) Cooling from the drop in air pressure which occurs with uplift of air, also known asadiabatic cooling. Air can be lifted by mountains, which deflect the air upward, by convection, and by cold and warm fronts. 3) Advective cooling - cooling due to horizontal movement of air.
Importance and Uses
[edit]- Provides water for plants and animals: Water vapour gets converted to rain and snow that serve as a natural source of water for plants and animals.
- Controls evaporation: Excess water vapor in the air decreases the rate of evaporation.
- Determines climatic conditions: Excess water vapor in the air produces rain, fog, snow etc. Hence, it determines climatic conditions.
Chemical reactions
[edit]A number of chemical reactions have water as a product. If the reactions take place at temperatures higher than the dew point of the surrounding air the water will be formed as vapor and increase the local humidity, if below the dew point local condensation will occur. Typical reactions that result in water formation are the burning ofhydrogenorhydrocarbonsin air or otheroxygencontaining gas mixtures, or as a result of reactions with oxidizers.
In a similar fashion other chemical or physical reactions can take place in the presence of water vapor resulting in new chemicals forming such asruston iron or steel, polymerization occurring (certainpolyurethanefoams andcyanoacrylateglues cure with exposure to atmospheric humidity) or forms changing such as where anhydrous chemicals may absorb enough vapor to form a crystalline structure or alter an existing one, sometimes resulting in characteristic color changes that can be used formeasurement.
Measurement
[edit]Measuring the quantity of water vapor in a medium can be done directly or remotely with varying degrees of accuracy. Remote methods suchelectromagnetic absorptionare possible from satellites above planetary atmospheres. Direct methods may use electronic transducers, moistened thermometers or hygroscopic materials measuring changes in physical properties or dimensions.
medium | temperature range (degC) | measurementuncertainty | typical measurement frequency | system cost | notes | |
---|---|---|---|---|---|---|
Sling psychrometer | air | −10 to 50 | low to moderate | hourly | low | |
Satellite-based spectroscopy | air | −80 to 60 | low | very high | ||
Capacitivesensor | air/gases | −40 to 50 | moderate | 2 to 0.05 Hz | medium | prone to becoming saturated/contaminated over time |
Warmed capacitive sensor | air/gases | −15 to 50 | moderate to low | 2 to 0.05 Hz (temp dependant) | medium to high | prone to becoming saturated/contaminated over time |
Resistivesensor | air/gases | −10 to 50 | moderate | 60 seconds | medium | prone to contamination |
Lithium chloridedewcell | air | −30 to 50 | moderate | continuous | medium | seedewcell |
Cobalt(II) chloride | air/gases | 0 to 50 | high | 5 minutes | very low | often used inHumidity indicator card |
Absorption spectroscopy | air/gases | moderate | high | |||
Aluminum oxide | air/gases | moderate | medium | seeMoisture analysis | ||
Silicon oxide | air/gases | moderate | medium | seeMoisture analysis | ||
Piezoelectric sorption | air/gases | moderate | medium | seeMoisture analysis | ||
Electrolytic | air/gases | moderate | medium | seeMoisture analysis | ||
Hair tension | air | 0 to 40 | high | continuous | low to medium | Affected by temperature. Adversely affected by prolonged high concentrations |
Nephelometer | air/other gases | low | very high | |||
Goldbeater's skin(Cow Peritoneum) | air | −20 to 30 | moderate (with corrections) | slow, slower at lower temperatures | low | ref:WMO Guide to Meteorological Instruments and Methods of Observation No. 8 2006, (pages 1.12–1) |
Lyman- Alpha | high frequency | high | http://amsglossary.allenpress /glossary/search?id=lyman- Alpha -hygrometer1Requires frequent calibration | |||
GravimetricHygrometer | very low | very high | often called primary source, national independent standards developed in US, UK, EU & Japan | |||
medium | temperature range (degC) | measurementuncertainty | typical measurement frequency | system cost | notes |
Impact on air density
[edit]Water vapor is lighter or lessdense than dry air.[11][12]At equivalent temperatures it is buoyant with respect to dry air, whereby the density of dry air atstandard temperature and pressure(273.15 K, 101.325 kPa) is 1.27 g/L and water vapor at standard temperature has avapor pressureof 0.6 kPa and the much lower density of 0.0048 g/L.
Calculations
[edit]Water vapor and dry air density calculations at 0 °C:
- Themolar massof water is18.02 g/mol,as calculated from the sum of theatomic massesof its constituentatoms.
- The average molar mass of air (approx. 78% nitrogen, N2;21% oxygen, O2;1% other gases) is28.57 g/molat standard temperature and pressure (STP).
- ObeyingAvogadro's Lawand theideal gas law,moist airwill have a lower density than dry air. At max. saturation (i. e. rel. humidity = 100% at 0 °C) the density will go down to 28.51 g/mol.
- STP conditions imply a temperature of 0 °C, at which the ability of water to become vapor is very restricted. Itsconcentrationin air is very low at 0 °C. The red line on the chart to the right is the maximum concentration of water vapor expected for a given temperature. The water vapor concentration increases significantly as the temperature rises, approaching 100% (steam,pure water vapor) at 100 °C. However the difference in densities between air and water vapor would still exist (0.598 vs. 1.27 g/L).
At equal temperatures
[edit]At the same temperature, a column of dry air will be denser or heavier than a column of air containing any water vapor, the molar mass of diatomicnitrogenand diatomicoxygenboth being greater than the molar mass of water. Thus, any volume of dry air will sink if placed in a larger volume of moist air. Also, a volume of moist air will rise or bebuoyantif placed in a larger region of dry air. As the temperature rises the proportion of water vapor in the air increases, and its buoyancy will increase. The increase in buoyancy can have a significant atmospheric impact, giving rise to powerful, moisture rich, upward air currents when the air temperature and sea temperature reaches 25 °C or above. This phenomenon provides a significant driving force forcyclonicandanticyclonicweather systems (typhoons and hurricanes).
Respiration and breathing
[edit]Water vapor is a by-product ofrespirationin plants and animals. Its contribution to the pressure, increases as its concentration increases. Itspartial pressurecontribution to air pressure increases, lowering the partial pressure contribution of the other atmospheric gases(Dalton's Law).The total air pressure must remain constant. The presence of water vapor in the air naturally dilutes or displaces the other air components as its concentration increases.
This can have an effect on respiration. In very warm air (35 °C) the proportion of water vapor is large enough to give rise to the stuffiness that can be experienced in humid jungle conditions or in poorly ventilated buildings.
Lifting gas
[edit]Water vapor has lower density than that ofairand is thereforebuoyantin air but has lower vapor pressure than that of air. When water vapor is used as alifting gasby athermal airshipthe water vapor is heated to form steam so that its vapor pressure is greater than the surrounding air pressure in order to maintain the shape of a theoretical "steam balloon", which yields approximately 60% the lift of helium and twice that of hot air.[13]
General discussion
[edit]The amount of water vapor in an atmosphere is constrained by the restrictions of partial pressures and temperature. Dew point temperature and relative humidity act as guidelines for the process of water vapor in thewater cycle.Energy input, such as sunlight, can trigger more evaporation on an ocean surface or more sublimation on a chunk of ice on top of a mountain. Thebalancebetween condensation and evaporation gives the quantity calledvapor partial pressure.
The maximum partial pressure (saturation pressure) of water vapor in air varies with temperature of the air and water vapor mixture. A variety of empirical formulas exist for this quantity; the most used reference formula is theGoff-Gratch equationfor the SVP over liquid water below zero degrees Celsius:
whereT,temperature of the moist air, is given in units ofkelvin,andpis given in units ofmillibars(hectopascals).
The formula is valid from about −50 to 102 °C; however there are a very limited number of measurements of the vapor pressure of water over supercooled liquid water. There are a number of other formulae which can be used.[14]
Under certain conditions, such as when the boiling temperature of water is reached, a net evaporation will always occur during standard atmospheric conditions regardless of the percent of relative humidity. This immediate process will dispel massive amounts of water vapor into a cooler atmosphere.
Exhaledair is almost fully at equilibrium with water vapor at the body temperature. In the cold air the exhaled vapor quickly condenses, thus showing up as a fog ormistof water droplets and as condensation or frost on surfaces. Forcibly condensing these water droplets from exhaled breath is the basis ofexhaled breath condensate,an evolving medical diagnostic test.
Controlling water vapor in air is a key concern in theheating, ventilating, and air-conditioning(HVAC) industry.Thermal comfortdepends on the moist air conditions. Non-human comfort situations are calledrefrigeration,and also are affected by water vapor. For example, many food stores, like supermarkets, utilize open chiller cabinets, orfood cases,which can significantly lower the water vapor pressure (lowering humidity). This practice delivers several benefits as well as problems.
In Earth's atmosphere
[edit]Gaseous water represents a small but environmentally significant constituent of theatmosphere.The percentage of water vapor in surface air varies from 0.01% at -42 °C (-44 °F)[15]to 4.24% when the dew point is 30 °C (86 °F).[16]Over 99% of atmospheric water is in the form of vapour, rather than liquid water or ice,[17]and approximately 99.13% of the water vapour is contained in thetroposphere.Thecondensationof water vapor to the liquid or ice phase is responsible forclouds,rain, snow, and otherprecipitation,all of which count among the most significant elements of what we experience as weather. Less obviously, thelatent heat of vaporization,which is released to the atmosphere whenever condensation occurs, is one of the most important terms in theatmospheric energy budgeton both local and global scales. For example, latent heat release in atmosphericconvectionis directly responsible for powering destructive storms such astropical cyclonesand severethunderstorms.Water vapor is an importantgreenhouse gas[18][19]owing to the presence of thehydroxylbond which strongly absorbs in theinfra-red.
Water vapor is the "working medium" of the atmospheric thermodynamic engine which transforms heat energy from sun irradiation into mechanical energy in the form of winds. Transforming thermal energy into mechanical energy requires an upper and a lower temperature level, as well as a working medium which shuttles forth and back between both. The upper temperature level is given by the soil or water surface of the Earth, which absorbs the incoming sun radiation and warms up, evaporating water. The moist and warm air at the ground is lighter than its surroundings and rises up to the upper limit of the troposphere. There the water molecules radiate their thermal energy into outer space, cooling down the surrounding air. The upper atmosphere constitutes the lower temperature level of the atmospheric thermodynamic engine. The water vapor in the now cold air condenses out and falls down to the ground in the form of rain or snow. The now heavier cold and dry air sinks down to ground as well; the atmospheric thermodynamic engine thus establishes a vertical convection, which transports heat from the ground into the upper atmosphere, where the water molecules can radiate it to outer space. Due to the Earth's rotation and the resulting Coriolis forces, this vertical atmospheric convection is also converted into a horizontal convection, in the form of cyclones and anticyclones, which transport the water evaporated over the oceans into the interior of the continents, enabling vegetation to grow.[20]
Water in Earth's atmosphere is not merely below its boiling point (100 °C), butat altitudeitgoes belowits freezing point (0 °C), due to water'shighly polar attraction.When combined with its quantity, water vapor then has a relevantdew pointandfrost point,unlike e. g., carbon dioxide and methane. Water vapor thus has ascale heighta fraction of that of the bulk atmosphere,[21][22][23]as the watercondensesandexits,primarily in thetroposphere,the lowest layer of the atmosphere.[24]Carbon dioxide (CO2) andmethane,being well-mixed in the atmosphere, tend to rise above water vapour. The absorption and emission of both compounds contribute to Earth's emission to space, and thus theplanetary greenhouse effect.[22][25][26]This greenhouse forcing is directly observable, via distinctspectral featuresversus water vapor, and observed to be rising with rising CO2levels.[27]Conversely, adding water vapor at high altitudes has a disproportionate impact, which is whyjet traffic[28][29][30]has a disproportionately high warming effect. Oxidation of methane is also a major source of water vapour in the stratosphere,[31]and adds about 15% to methane's global warming effect.[32]
In the absence of other greenhouse gases, Earth's water vapor would condense to the surface;[33][34][35]thishas likely happened,possibly more than once. Scientists thus distinguish between non-condensable (driving) and condensable (driven) greenhouse gases, i.e., the above water vapor feedback.[36][19][18]
Fogand clouds form through condensation aroundcloud condensation nuclei.In the absence of nuclei, condensation will only occur at much lower temperatures. Under persistent condensation or deposition, cloud droplets or snowflakes form, whichprecipitatewhen they reach a critical mass.
Atmospheric concentration of water vapour is highly variable between locations and times, from 10 ppmv in the coldest air to 5% (50 000 ppmv) in humid tropical air,[37]and can be measured with a combination of land observations, weather balloons and satellites.[38]The water content of the atmosphere as a whole is constantly depleted by precipitation. At the same time it is constantly replenished by evaporation, most prominently from oceans, lakes, rivers, and moist earth. Other sources of atmospheric water include combustion, respiration, volcanic eruptions, the transpiration of plants, and various other biological and geological processes. At any given time there is about 1.29 x 1016litres (3.4 x 1015gal.) of water in the atmosphere. The atmosphere holds 1 part in 2500 of the fresh water, and 1 part in 100,000 of the total water on Earth.[39]The mean global content of water vapor in the atmosphere is roughly sufficient to cover the surface of the planet with a layer of liquid water about 25 mm deep.[40][41][42]The mean annual precipitation for the planet is about 1 metre, a comparison which implies a rapid turnover of water in the air – on average, the residence time of a water molecule in thetroposphereis about 9 to 10 days.[42]
Global mean water vapour is about 0.25% of the atmosphere by mass and also varies seasonally, in terms of contribution to atmospheric pressure between 2.62 hPa in July and 2.33 hPa in December.[45]IPCC AR6expresses medium confidence in increase of total water vapour at about 1-2% per decade;[46]it is expected toincreaseby around 7% per °C of warming.[40]
Episodes of surface geothermal activity, such as volcanic eruptions and geysers, release variable amounts of water vapor into the atmosphere. Such eruptions may be large in human terms, and major explosive eruptions may inject exceptionally large masses of water exceptionally high into the atmosphere, but as a percentage of total atmospheric water, the role of such processes is trivial. The relative concentrations of the various gases emitted byvolcanoesvaries considerably according to the site and according to the particular event at any one site. However, water vapor is consistently the commonestvolcanic gas;as a rule, it comprises more than 60% of total emissions during asubaerial eruption.[47]
Atmospheric water vapor content is expressed using various measures. These include vapor pressure,specific humidity,mi xing ratio, dew point temperature, andrelative humidity.
Radar and satellite imaging
[edit]Because water moleculesabsorbmicrowavesand otherradio wavefrequencies, water in the atmosphere attenuatesradarsignals.[48]In addition, atmospheric water willreflectandrefractsignals to an extent that depends on whether it is vapor, liquid or solid.
Generally, radar signals lose strength progressively the farther they travel through the troposphere. Different frequencies attenuate at different rates, such that some components of air are opaque to some frequencies and transparent to others. Radio waves used for broadcasting and other communication experience the same effect.
Water vapor reflects radar to a lesser extent than do water's other two phases. In the form of drops and ice crystals, water acts as a prism, which it does not do as an individualmolecule;however, the existence of water vapor in the atmosphere causes the atmosphere to act as a giant prism.[49]
A comparison ofGOES-12satellite images shows the distribution of atmospheric water vapor relative to the oceans, clouds and continents of the Earth. Vapor surrounds the planet but is unevenly distributed. The image loop on the right shows monthly average of water vapor content with the units are given in centimeters, which is theprecipitable wateror equivalent amount of water that could be produced if all the water vapor in the column were to condense. The lowest amounts of water vapor (0 centimeters) appear in yellow, and the highest amounts (6 centimeters) appear in dark blue. Areas of missing data appear in shades of gray. The maps are based on data collected by theModerate Resolution Imaging Spectroradiometer(MODIS) sensor on NASA's Aqua satellite. The most noticeable pattern in the time series is the influence of seasonal temperature changes and incoming sunlight on water vapor. In the tropics, a band of extremely humid air wobbles north and south of the equator as the seasons change. This band of humidity is part of theIntertropical Convergence Zone,where the easterly trade winds from each hemisphere converge and produce near-daily thunderstorms and clouds. Farther from the equator, water vapor concentrations are high in the hemisphere experiencing summer and low in the one experiencing winter. Another pattern that shows up in the time series is that water vapor amounts over land areas decrease more in winter months than adjacent ocean areas do. This is largely because air temperatures over land drop more in the winter than temperatures over the ocean. Water vapor condenses more rapidly in colder air.[50]
As water vapor absorbs light in the visible spectral range, its absorption can be used in spectroscopic applications (such asDOAS) to determine the amount of water vapor in the atmosphere. This is done operationally, e.g. from the GlobalOzoneMonitoring Experiment (GOME) spectrometers onERS(GOME) andMetOp(GOME-2).[51]The weaker water vapor absorption lines in the blue spectral range and further into the UV up to its dissociation limit around 243 nm are mostly based on quantum mechanical calculations[52]and are only partly confirmed by experiments.[53]
Lightning generation
[edit]Water vapor plays a key role inlightningproduction in the atmosphere. Fromcloud physics,usually clouds are the real generators of staticchargeas found in Earth's atmosphere. The ability of clouds to hold massive amounts of electrical energy is directly related to the amount of water vapor present in the local system.
The amount of water vapor directly controls thepermittivityof the air. During times of low humidity, static discharge is quick and easy. During times of higher humidity, fewer static discharges occur. Permittivity and capacitance work hand in hand to produce the megawatt outputs of lightning.[54]
After a cloud, for instance, has started its way to becoming a lightning generator, atmospheric water vapor acts as a substance (orinsulator) that decreases the ability of the cloud todischargeits electrical energy. Over a certain amount of time, if the cloud continues to generate and store morestatic electricity,the barrier that was created by the atmospheric water vapor will ultimately break down from the stored electrical potential energy.[55]This energy will be released to a local oppositely charged region, in the form of lightning. The strength of each discharge is directly related to the atmospheric permittivity, capacitance, and the source's charge generating ability.[56]
Extraterrestrial
[edit]Water vapor is common in theSolar Systemand by extension, otherplanetary systems.Its signature has been detected in the atmospheres of the Sun, occurring insunspots.The presence of water vapor has been detected in the atmospheres of all seven extraterrestrial planets in the Solar System, the Earth's Moon,[57]and the moons of other planets,[which?]although typically in only trace amounts.
Geological formations such ascryogeysersare thought to exist on the surface of severalicy moonsejecting water vapor due totidal heatingand may indicate the presence of substantial quantities of subsurface water. Plumes of water vapor have been detected on Jupiter's moonEuropaand are similar to plumes of water vapor detected on Saturn's moonEnceladus.[58]Traces of water vapor have also been detected in the stratosphere ofTitan.[60]Water vapor has been found to be a major constituent of the atmosphere ofdwarf planet,Ceres,largest object in theasteroid belt[61]The detection was made by using thefar-infrared abilitiesof theHerschel Space Observatory.[62]The finding is unexpected becausecomets,notasteroids,are typically considered to "sprout jets and plumes." According to one of the scientists, "The lines are becoming more and more blurred between comets and asteroids."[62]Scientists studyingMarshypothesize that if water moves about the planet, it does so as vapor.[63]
The brilliance ofcomettails comes largely from water vapor. On approach to theSun,the ice many comets carrysublimesto vapor. Knowing a comet's distance from the sun, astronomers may deduce the comet's water content from its brilliance.[64]
Water vapor has also been confirmed outside the Solar System. Spectroscopic analysis ofHD 209458 b,an extrasolar planet in the constellation Pegasus, provides the first evidence of atmospheric water vapor beyond the Solar System. A star calledCW Leoniswas found to have a ring of vast quantities of water vapor circling the aging, massivestar.ANASAsatellite designed to study chemicals in interstellar gas clouds, made the discovery with an onboard spectrometer. Most likely, "the water vapor was vaporized from the surfaces of orbiting comets."[65]Other exoplanets with evidence of water vapor includeHAT-P-11bandK2-18b.[66][67]
See also
[edit]- Air density
- Atmospheric river
- Boiling point
- Condensation in aerosol dynamics
- Deposition
- Earth's atmosphere
- Eddy covariance
- Equation of state
- Evaporative cooler
- Fog
- Frost
- Gas laws
- Gibbs free energy
- Gibbs phase rule
- Greenhouse gas
- Heat capacity
- Heat of vaporization
- Humidity
- Hygrometer
- Ideal gas
- Kinetic theory of gases
- Latent heat
- Latent heat flux
- Microwave radiometer
- Phase of matter
- Saturation vapor density
- Steam
- Sublimation
- Superheating
- Supersaturation
- Thermodynamics
- Troposphere
- Vapor pressure
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