Carbon
![]() Graphite (left) and diamond (right), two allotropes of carbon | |||||||||||||||||||||||||||||||
Carbon | |||||||||||||||||||||||||||||||
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Allotropes | graphite,diamondand more (seeAllotropes of carbon) | ||||||||||||||||||||||||||||||
Appearance | graphite: black diamond: clear | ||||||||||||||||||||||||||||||
Standard atomic weightAr°(C) | |||||||||||||||||||||||||||||||
[12.0096,12.0116][1] | |||||||||||||||||||||||||||||||
Carbon in theperiodic table | |||||||||||||||||||||||||||||||
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Group | group 14 (carbon group) | ||||||||||||||||||||||||||||||
Period | period 2 | ||||||||||||||||||||||||||||||
Block | p-block | ||||||||||||||||||||||||||||||
Electron configuration | [He] 2s22p2 | ||||||||||||||||||||||||||||||
Electrons per shell | 2, 4 | ||||||||||||||||||||||||||||||
Physical properties | |||||||||||||||||||||||||||||||
PhaseatSTP | solid | ||||||||||||||||||||||||||||||
Sublimation point | 3915 K (3642 °C, 6588 °F) | ||||||||||||||||||||||||||||||
Density(nearr.t.) | amorphous: 1.8–2.1 g/cm3[2] graphite: 2.267 g/cm3 diamond: 3.515 g/cm3 | ||||||||||||||||||||||||||||||
Triple point | 4600 K, 10,800 kPa[3][4] | ||||||||||||||||||||||||||||||
Heat of fusion | graphite: 117kJ/mol | ||||||||||||||||||||||||||||||
Molar heat capacity | graphite: 8.517 J/(mol·K) diamond: 6.155 J/(mol·K) | ||||||||||||||||||||||||||||||
Atomic properties | |||||||||||||||||||||||||||||||
Oxidation states | −4,−3,−2,−1,0,+1,[5]+2,+3,[6]+4[7](a mildlyacidicoxide) | ||||||||||||||||||||||||||||||
Electronegativity | Pauling scale: 2.55 | ||||||||||||||||||||||||||||||
Ionization energies |
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Covalent radius | sp3:77 pm sp2:73 pm sp: 69pm | ||||||||||||||||||||||||||||||
Van der Waals radius | 170 pm | ||||||||||||||||||||||||||||||
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Other properties | |||||||||||||||||||||||||||||||
Natural occurrence | primordial | ||||||||||||||||||||||||||||||
Crystal structure | graphite: simple hexagonal (black) | ||||||||||||||||||||||||||||||
Crystal structure | diamond: face-centered diamond-cubic (clear) | ||||||||||||||||||||||||||||||
Speed of soundthin rod | diamond: 18,350 m/s (at 20 °C) | ||||||||||||||||||||||||||||||
Thermal expansion | diamond: 0.8 µm/(m⋅K) (at 25 °C)[8] | ||||||||||||||||||||||||||||||
Thermal conductivity | graphite: 119–165 W/(m⋅K) diamond: 900–2300 W/(m⋅K) | ||||||||||||||||||||||||||||||
Electrical resistivity | graphite: 7.837 µΩ⋅m[9] | ||||||||||||||||||||||||||||||
Magnetic ordering | diamagnetic[10] | ||||||||||||||||||||||||||||||
Molar magnetic susceptibility | −5.9·10−6(graph.) cm3/mol[11] | ||||||||||||||||||||||||||||||
Young's modulus | diamond: 1050 GPa[8] | ||||||||||||||||||||||||||||||
Shear modulus | diamond: 478 GPa[8] | ||||||||||||||||||||||||||||||
Bulk modulus | diamond: 442 GPa[8] | ||||||||||||||||||||||||||||||
Poisson ratio | diamond: 0.1[8] | ||||||||||||||||||||||||||||||
Mohs hardness | graphite: 1–2 diamond: 10 | ||||||||||||||||||||||||||||||
CAS Number | 7440-44-0 | ||||||||||||||||||||||||||||||
History | |||||||||||||||||||||||||||||||
Discovery | EgyptiansandSumerians[12](3750 BCE) | ||||||||||||||||||||||||||||||
Recognized as an element by | Antoine Lavoisier[13](1789) | ||||||||||||||||||||||||||||||
Isotopes of carbon | |||||||||||||||||||||||||||||||
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Carbonis a very importantchemical element,with achemical symbolofC.All knownlifeonEarthneeds it to survive. Carbon hasatomic mass12 andatomic number6. It is anonmetal,meaning that it is not ametal.
Whenironisalloyedwith carbon, hardsteelis formed. Carbon in the form ofcoalis an importantfuel.
Chemistry of carbon
[change|change source]A whole type of chemistry, calledorganic chemistry,is about carbon and itscompounds.Carbon makes many types of compounds.Hydrocarbonsare molecules with carbon and hydrogen.Methane,Propane,and many otherfuelsare hydrocarbons. Many of the substances that people use daily are organic compounds.
Carbon,hydrogen,nitrogen,oxygen,and some other elements likesulfurandphosphorustogether form most life onearth(seeList of biologically important elements). Carbon forms a very large number oforganic compoundsbecause it can form strongbondswith itself and with other elements. Because of the amounts of carbon living things have, all organic things are considered "carbon-based".
Each carbon atom usually forms fourchemical bonds,which are strong connections to other atoms to formmolecules.The kind of bond that carbon makes is called acovalent bond.These bonds allow carbon to form many kinds of small and large molecules. A molecule ofmethaneis the smallest; it has fourhydrogenatoms bonded to carbon. The bonds can bedouble bonds,meaning that two bonds form between carbon and another atom to make a stronger connection. For example,carbon dioxidehas twooxygenatoms, and each one is double bonded to carbon. Carbon can even form three bonds with another atom, called atriple bond.For example, in the gasacetylenecarbon forms a triple bond with another carbon atom.
By bonding to other carbon atoms, carbon can form long chain-shapedmolecules,calledpolymers,such asplasticsandproteins.Atoms of other elements can be part of the long polymer chains, often nitrogen or oxygen.
Pure carbon formsdiamondby bonding to four other carbon atoms in athree dimensionalcrystal.It formsgraphiteby bonding to three other carbon atoms to form thin flat layers.
Etymology
[change|change source]The name of carbon comes fromLatincarbo,meaningcharcoal.In many foreign languages the words for carbon,coaland charcoal are synonyms.
Types of carbon
[change|change source]Carbon innatureis found in three forms calledallotropes:diamond,graphite,andfullerenes.Graphite, withclay,is inpencils.It is very soft. The carbon atoms in it make rings, which are on top of each other and slide very easily. Diamonds are the hardest naturalmineral.Fullerenes are a "soccerball "shape of carbon. They are mostly of interest toscience.A special, man-made, tube-shaped allotrope of carbon is thecarbon nanotube.Carbon nanotubes are very hard, so they might be used inarmor.Nanotubes might be useful innanotechnology.
There are 10 million known carboncompounds.
![](https://upload.wikimedia.org/wikipedia/commons/thumb/f/f8/Eight_Allotropes_of_Carbon.png/350px-Eight_Allotropes_of_Carbon.png)
Radiocarbon dating
[change|change source]Aradioactiveisotopeof carbon, carbon-14, can be used to figure out how old some objects are or when something died. As long as something is on the surface of the earth and taking in carbon, the amount of carbon-14 stays the same. When an object stops taking in carbon, the carbon-14 amount goes down. Because thehalf-life(how long it takes for half of a radioactive isotope to go away) of carbon-14 is 5730 years,[17]scientistscan see how old the object is by how much carbon-14 is left.
Where carbon is
[change|change source]Carbon is in many places in the universe. It was first made in oldstars.Carbon is the fourth most common element in thesun.[17]TheatmospheresofVenusandMarsare mostlycarbon dioxide.[18]
Carbon is important to thehuman bodyand otherliving things,and it is the second most common element in the human body, at 23% of all body weight.[17]It is also a key part of many biological molecules (moleculesused in life).
Most of the carbon on Earth iscoal.Graphiteis in many (typicallydesert) areas, includingSri Lanka,Madagascar,andRussia.Diamonds are rare and are found largely inAfrica.Carbon is also in some meteorites.
Related pages
[change|change source]References
[change|change source]- ↑"Standard Atomic Weights: Carbon".CIAAW.2009.
- ↑Lide, D. R., ed. (2005).CRC Handbook of Chemistry and Physics(86th ed.). Boca Raton (FL): CRC Press.ISBN0-8493-0486-5.
- ↑Haaland, D (1976). "Graphite-liquid-vapor triple point pressure and the density of liquid carbon".Carbon.14(6): 357–361.doi:10.1016/0008-6223(76)90010-5.
- ↑Savvatimskiy, A (2005). "Measurements of the melting point of graphite and the properties of liquid carbon (a review for 1963–2003)".Carbon.43(6): 1115–1142.doi:10.1016/j.carbon.2004.12.027.
- ↑"Fourier Transform Spectroscopy of the Electronic Transition of the Jet-Cooled CCI Free Radical"(PDF).Retrieved2007-12-06.
- ↑"Fourier Transform Spectroscopy of the System of CP"(PDF).Retrieved2007-12-06.
- ↑"Carbon: Binary compounds".Retrieved2007-12-06.
- ↑8.08.18.28.38.4Properties of diamond,Ioffe Institute Database
- ↑"Material Properties- Misc Materials".www.nde-ed.org.Retrieved12 November2016.
- ↑Magnetic susceptibility of the elements and inorganic compounds,in Handbook of Chemistry and Physics 81st edition, CRC press.
- ↑Weast, Robert (1984).CRC, Handbook of Chemistry and Physics.Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110.ISBN0-8493-0464-4.
- ↑"History of Carbon and Carbon Materials - Center for Applied Energy Research - University of Kentucky".Caer.uky.edu.Retrieved2008-09-12.
- ↑Senese, Fred (2000-09-09)."Who discovered carbon?".Frostburg State University.Retrieved2007-11-24.
- ↑"Fourier Transform Spectroscopy of the System of CP"(PDF).Retrieved2007-12-06.
- ↑"Fourier Transform Spectroscopy of the Electronic Transition of the Jet-Cooled CCI Free Radical"(PDF).Retrieved2007-12-06.
- ↑"Carbon: Binary compounds".Retrieved2007-12-06.
- ↑17.017.117.2Emsley, John (2001).Nature's Building blocks.Oxford University Press.ISBN0-19-850341-5.
- ↑University of Sheffield and Webelements Ltd. (2007)."Chemistry: Periodic Table: carbon: key information".
Other websites
[change|change source]H | He | ||||||||||||||||||||||||||||||||||||||||
Li | Be | B | C | N | O | F | Ne | ||||||||||||||||||||||||||||||||||
Na | Mg | Al | Si | P | S | Cl | Ar | ||||||||||||||||||||||||||||||||||
K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr | ||||||||||||||||||||||||
Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe | ||||||||||||||||||||||||
Cs | Ba | La | Ce | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl | Pb | Bi | Po | At | Rn | ||||||||||
Fr | Ra | Ac | Th | Pa | U | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | ||||||||||
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